403655-45-8

Basic information

• Product Name: (3S,6S)-(-)-6-(1-benzoyloxyindol-3-ylmethyl)-3-isobutyl-2,5-piperazinedione
• Synonyms: (3S,6S)-(-)-6-(1-benzoyloxyindol-3-ylmethyl)-3-isobutyl-2,5-piperazinedione
• CAS NO: 403655-45-8
• Molecular Weight: 419.48
• Mol File: 403655-45-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: (3S,6S)-(-)-6-(1-benzoyloxyindol-3-ylmethyl)-3-isobutyl-2,5-piperazinedione(CAS DataBase Reference)
• NIST Chemistry Reference: (3S,6S)-(-)-6-(1-benzoyloxyindol-3-ylmethyl)-3-isobutyl-2,5-piperazinedione(403655-45-8)
• EPA Substance Registry System: (3S,6S)-(-)-6-(1-benzoyloxyindol-3-ylmethyl)-3-isobutyl-2,5-piperazinedione(403655-45-8)

Safety Data

• Hazardous Substances Data: 403655-45-8(Hazardous Substances Data)

Upstream product

• 7432-21-5 N-carbobenzyloxy-L-tryptophane 
• 2419-36-5 Cbz-Trp-Leu-OMe 
• 54793-76-9 L-tryptophan-L-leucine methylester 
• 403655-37-8 (3S,6S)-6-[(3RS)-2,3-dihydroindol-3-ylmethyl]-3-isobutyl-2,5-piperazinedione 
• 56941-94-7 Cyclo(L-leucyl-L-tryptophyl) 
• 2666-93-5 (S)-Leu-OMe 
• 98-88-4 benzoyl chloride 
• 180910-60-5 (3S,6S)-(–)-6-(1-hydroxyindol-3-ylmethyl)-3-isobutyl-2,5-piperazinedione 

Relevant articles and documents

A [3,3] sigmatropic and novel ipso [3,3] sigmatropic rearrangement of 1-hydroxyindole chemistry

Utilizing 1-aryloxyindole derivatives, we found a new type of [3,3] sigmatropic rearrangement reaction. We named it as ipso [3,3] sigmatropic rearrangement. The product structures are strictly determined by X-ray crystallographic analysis. Normal [3,3] sigmatropic rearrangement of 1-hydroxyindole derivative was found to be a useful synthetic method for 2H-pyrazino[1',2':1,5]pyrrolo[2,3-b]indole-1,4-dione derivative.