403705-98-6Relevant academic research and scientific papers
Pd-catalyzed decarboxylative ortho-acylation of O-methyl oximes with phenylglyoxylic acids
Yang, Zhiyong,Chen, Xiang,Liu, Jidan,Gui, Qingwen,Xie, Kai,Li, Miaomiao,Tan, Ze
supporting information, p. 1560 - 1562 (2013/03/13)
Aryl ketones were synthesized via Pd-catalyzed decarboxylative coupling between O-methyl oximes and phenylglyoxylic acids using (NH4) 2S2O8 as the oxidant. The Royal Society of Chemistry 2013.
Reactions of 1-(2-alkoxyphenyl)alkaniminyl radicals
Leardini, Rino,McNab, Hamish,Minozzi, Matteo,Nanni, Daniele,Reed, David,Wright, Andrew G.
, p. 2704 - 2710 (2007/10/03)
Reactions of 1-(2-alkoxyphenyl)alkaniminyl radicals were studied. Generation of the iminyls 1d and 1e by standard methods in the gas-phase by flash vacuum pyrolysis (FVP) gives rise to 1,3-benzoxazines 18 and 22 by a mechanism which probably involves a 1,6-hydrogen atom translocation. The results showed that the dealkylation is an integral part of the reaction mechanism and not a subsequent reaction of 2-alkoxybenzonitriles.
