40468-86-8

Usage

Synthesis Reference(s)

Chemical and Pharmaceutical Bulletin, 18, p. 511, 1970 DOI: 10.1248/cpb.18.511

Upstream product

• 88785-71-1 Phenyl-[1-pyridin-2-yl-meth-(Z)-ylidene]-amine 
• 1121-60-4 pyridine-2-carbaldehyde 
• 62-53-3 aniline 
• 29202-13-9 N-(p-dimethylaminophenyl)pyridine-2-aldimine 
• 42910-72-5 (E)-4-methyl-N-(( pyridin-2-yl)methylene)aniline 
• 25100-42-9 4-{[1-Pyridin-2-yl-meth-(E)-ylidene]-amino}-benzoic acid ethyl ester 
• 26930-67-6 (E)-N-(4-methoxyphenyl)-1-(pyridin-2-yl)methanimine 

Downstream Products

• 1066-40-6 Trimethylsilanol 
• 62-53-3 aniline 
• 13341-40-7 (E)-1,2-bis(2-pyridyl)ethene 
• 79388-25-3 methyl 2,2-dimethyl-3-(phenylamino)-3-(2-pyridyl)propanoate 
• 110362-28-2 4-Methyl-1-phenyl-6-(2-pyridyl)-5,6-dihydropyridin-2-one 
• 42910-72-5 (E)-4-methyl-N-(( pyridin-2-yl)methylene)aniline 
• 26930-67-6 (E)-N-(4-methoxyphenyl)-1-(pyridin-2-yl)methanimine 
• 29202-13-9 N-(p-dimethylaminophenyl)pyridine-2-aldimine 
• 25100-42-9 4-{[1-Pyridin-2-yl-meth-(E)-ylidene]-amino}-benzoic acid ethyl ester 

Relevant academic research and scientific papers

193. Photoformation of (Z)-Isomers in Diarylazomethines. Part IV. Direct and Sensitized Photoisomerization of Pyridyl Analogues of Benzylidene-aniline and Absorption Spectra of their (Z)-Isomers

UV irradiation of solutions of the (E)-isomers of five (out of the possible six) monopyridyl analogues at reduced temperatures results in extensive (80-90percent) conversion into the corresponding (Z)-isomers.The process is reversible both thermally and photochemically.The (Z)-isomers are stable at temperatures below -80 deg, and their absorption spectra were estimated.Biacetyl-photosensitized (E)->(Z) isomerization was observed, with (Z)-contents of ca. 70percent at the photostationary state.

Far-red luminescent ruthenium pyridylimine complexes; Building blocks for multinuclear arrays

Ruthenium(ii) pyridylimine complexes are explored for their potential as units that might be incorporated into electronic or photonic arrays. The complexes [Ru(bipy)2(L)][PF6]2 (1) and [Ru(tpy)(L)Cl][BF4] (2) wi

Superelectrophilic Diels–Alder reactions and oxidations leading to heterocyclic biaryl compounds

Heterocyclic imines provide biaryl products by a two-step transformation. The first transformation involves a Diels–Alder reaction with a multiply protonated imine to give a tetrahydroquinoline product, whereas the second step involves oxidation with elem

Controlled Single and Double Iodofluorination of Alkynes with DIH- and HF-Based Reagents

A novel protocol for the regio- and stereoselective iodofluorination of internal and terminal alkynes using 1,3-diiodo-5,5,-dimethylhydantoin and HF-based reagents is disclosed. This approach is used to prepare a fluorinated tamoxifen derivative in two steps from commercially available starting materials. A facile method enabling controlled regioselective double iodofluorination of terminal alkynes is also presented.

Diels-Alder Reactions with Ethylene and Superelectrophiles

Diels-Alder reactions have been accomplished with ethylene as the dienophile through the use of inverse-electron demand Diels-Alder chemistry. As a key aspect of the chemistry, the dienes are part of tri- or dicationic superelectrophilic systems. Theoreti

Palladium(II) complexes containing N,N′-bidentate imine ligands derived from picolinaldehyde and substituted anilines: Synthesis, structure and polymerisation of methyl methacrylate

Palladium(II) complexes, LnPdCl2 (Ln = LA–LI), with N,N′-bidentate imine ligands derived from picolinaldehyde and substituted anilines have been synthesized and structurally characterized. Molecular structures revealed a distorted square plane geometry around Pd(II) centre in LnPdCl2 (Ln = LA–LC) obtained via coordination with pyridine and imine nitrogens and two chloro ligands. Pd(II) complexes LnPdCl2 (Ln = LA–LI) initiate polymerisation of methylmethacrylate (MMA) in the presence of modified methylaluminoxane (MMAO). The complex LIPdCl2 (of which the ligand was N-furfuryl substituted) showed the highest catalytic activity for the polymerisation of MMA with an activity of 7.08 × 104 g PMMA/mol·Pd·h at 60 °C. All the complexes yielded syndio-rich poly(methyl methacrylate) (PMMA) ([rr] = 0.70). Notably, the substituents on the imine moiety of the iminopyridine fragments affects the activities towards MMA polymerization, whereas the stereoselectivities remained unchanged.

Silver(I)-pyridinyl Schiff base complexes: Synthesis, characterisation and antimicrobial studies

Fifteen new silver(I)-pyridinyl complexes of the general formula [AgL2]X, where X = ClO4?, OTf or NO3?, were synthesised by reacting (E)-N-(pyridinylmethylene)aniline ligands and the respective silver

Silver(I)-pyridinyl Schiff base complexes: Synthesis, structural characterization and reactivity in ring-opening polymerisation of ε-caprolactone

Reactions of AgO2C2F3with 2-pyridinyl Schiff base ligands bore five novel complexes of the type [(AgO2C2F3)2.L2]: where L?=?L1, (E)-N-(1-(pyridin-2-yl)ethylidene)anili

Effect of the N-based ligands in copper complexes for depolymerisation of lignin

Several organic soluble N-based ligands and their copper complexes were firstly investigated as catalysts to depolymerise organosolv lignin in the organic solvent, dimethylformamide (DMF) and an ionic liquid (1-ethyl-3-methylimidazolium xylenesulfonate, [

PYRIDINE COMPLEX OF ZIRCONIUM, CATALYTIC SYSTEM COMPRISING SAID PYRIDINE COMPLEX OF ZIRCONIUM AND PROCESS OF (CO)POLYMERIZATION OF CONJUGATED DIENES

Pyridine complex of zirconium having general formula (I): ? Said pyridine complex of zirconium having general formula (I) may advantageously be used in a catalytic system for the (co)polymerization of conjugated dienes.