40709-05-5Relevant articles and documents
A general strategy for the stereocontrolled preparation of diverse 8- and 9-membered Laurencia -type bromoethers
Snyder, Scott A.,Treitler, Daniel S.,Brucks, Alexandria P.,Sattler, Wesley
, p. 15898 - 15901 (2011/11/13)
A unique procedure to effect a ring-expanding bromoetherification process is described, wherein tetrahydrofurans and tetrahydropyrans are smoothly transformed into 8- and 9-membered bromoethers in a regio- and stereocontrolled manner through the use of BDSB (bromodiethylsulfonium bromopentachloroantimonate). These products resemble the cores of the Laurencia C15 acetogenins. In light of the generality and effectiveness of the approach, this work provides a unique strategy for their laboratory preparation and may implicate a possible biosynthesis pathway.
Syntheses of the sex pheromone components of wild silk moths, fruit fly, melon fly and olive fly
Sharma,Sabharwal,Vohra,Sharma,Vig,Kad
, p. 31 - 33 (2007/10/02)
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SYNTHESIS OF SINGLE ISOMERS (E OR Z) OF UNSATURATED ALCOHOLS BY THE HORNER-WITTIG REACTION
Buss, Antony D,Greeves, Nicholas,Levin, Daniel,Wallace, Paul,Warren, Stuart
, p. 357 - 360 (2007/10/02)
Single isomers (E or Z) of homoallylic and higher alcohols can be synthesised from ω-hydroxyalkyldiphenylphosphine oxides and aldehydes, or from alkyldiphenylphosphine oxides and lactones
