4074-88-8

Usage

Chemical Properties

colourless liquid

Uses

Different sources of media describe the Uses of 4074-88-8 differently. You can refer to the following data:
1. Diethyleneglycol diacrylate is a cross-linking acrylate monomer for use in coatings, adhesives, and printing plates of prepolymer type.
2. Diethylene glycol diacrylate is used as reactive diluent and cross linking agent of radiation curing system, and also may be used as crosslinking resins, plastics and rubber modifier.

General Description

Clear colorless liquid with a mild musty odor.

Air & Water Reactions

Water soluble.

Reactivity Profile

Diethylene glycol diacrylate polymerizes at high temperatures. Diethylene glycol diacrylate is sensitive to light. Diethylene glycol diacrylate is incompatible with strong oxidizers, reducers, peroxides and other radical initiators.

Fire Hazard

Diethylene glycol diacrylate is combustible.

InChI:InChI=1/C10H14O5/c1-3-9(11)14-7-5-13-6-8-15-10(12)4-2/h3-4H,1-2,5-8H2

Upstream product

• 75-21-8 oxirane 
• 79-10-7 acrylic acid 
• 292638-85-8 acrylic acid methyl ester 
• 111-46-6 diethylene glycol 
• 814-68-6 acryloyl chloride 

Downstream Products

• 81165-45-9 3-[1-(3,4-Dimethoxy-benzyl)-6,7-dimethoxy-3,4-dihydro-1H-isoquinolin-2-yl]-propionic acid 2-(2-{3-[1-(3,4-dimethoxy-benzyl)-6,7-dimethoxy-3,4-dihydro-1H-isoquinolin-2-yl]-propionyloxy}-ethoxy)-ethyl ester; compound with oxalic acid 
• 447403-72-7 1-acryloyloxy-2-[2-(2-thiocyanato-3-phenylpropionyloxy)ethoxy]ethane 
• 447403-75-0 acrylic acid 2-[2-(2-thiocyanato-3-p-tolyl-propionyloxy)-ethoxy]-ethyl ester 
• 875916-85-1 acrylic acid 2-[2-(2-chloro-3-p-tolyl-propionyloxy)-ethoxy]-ethyl ester 

Relevant academic research and scientific papers

Method for catalytically synthesizing diethylene glycol di(methyl) acrylate by calcium glyceroxide

The invention discloses a method for catalytically synthesizing diethylene glycol di(methyl) acrylate by calcium glyceroxide, and belongs to the field of fine chemical engineering. (Methyl) alkyl acrylate and diethylene glycol are used as raw materials; a reaction-rectification coupling process is adopted; a copper-wire-net-filled modified rectification column is used; the catalyst calcium glyceroxide is added; enough product purity and yield can be obtained after a simple aftertreatment process. The method overcomes multiple disadvantages of an existing transesterification catalyst, and is high in yield and simple in post-processing. Compared with a conventional transesterification method, the method provided by the invention can improve the total yield and the processing capacity; energy needed for separation is supplied by utilizing reaction heat, so that the energy consumption is decreased, and an investment is reduced. The method provided by the invention is simple and short in process flow; the raw materials are easily obtained; equipment is simple; reaction conditions are easy to control. The method is mild in the reaction conditions and simple in purification and refining processes; a product is stable, is easy to separate, and is not liable to generate a polymerization phenomenon.

Low molecular weight PEI-based polycationic gene vectors via Michael addition polymerization with improved serum-tolerance

A series of polycationic gene delivery vectors were synthesized via Michael addition from low molecular weight PEI and linking compounds with various heteroatom compositions. Agarose gel electrophoresis results reveal that these polymers can well condense plasmid DNA and can protect DNA from degradation by nuclease. The formed polyplexes, which are stable toward serum, have uniform spherical nanoparticles with appropriate sizes around 200-350 nm and zeta-potentials about +40 mV. In vitro experiments show that these polymers have lower cytotoxicity and higher transfection efficiency than 25 KDa PEI. Furthermore, the title materials exhibit excellent serum tolerance. With the present of 10% serum, up to 19 times higher transfection efficiency than PEI was obtained, and no obvious decrease of TE was observed even the serum concentration was raised to >40%. Flow cytometry and confocal microscopy studies also demonstrate the good serum tolerance of the materials.

COMPOSITION FOR POLYELECTROLYTES, POLYELECTROLYTES, ELECTRICAL DOUBLE LAYER CAPACITORS AND NONAQUEOUS ELECTROLYTE SECONDARY CELLS

A polymer electrolyte-forming composition containing (A) a quaternary ammonium salt of general formula (1) below and (B) an ionic liquid can be converted into a polymer without compromising the excellent properties of the ionic liquid, thus enabling an electrolyte having an excellent safety and electrical conductivity and also a broad potential window to be obtained. In formula (1), R1 to R3 are each independently an alkyl group of 1 to 5 carbons or a substituent having a reactive unsaturated bond and any two from among R1 to R3 may together form a ring, and R4 is methyl, ethyl or a substituent having a reactive unsaturated bond, with the proviso that at least one of R1 to R4 is a substituent having a reactive unsaturated bond. X is a monovalent anion, the letter m is an integer from 1 to 8, and the letter n is an integer from 1 to 4.

METHOD FOR THE PRODUCTION OF HYDROXYALKYL CARBONIC ACID ESTERS

The invention relates to a heterogeneously catalyzed method for producing hydroxyalkyl carbonic acid esters from carbonic acids and alkylene oxides and the use thereof.

Process for the alkoxylation of organic compounds in the presence of novel framework materials

The present invention relates to a process for the alkoxylation of organic compounds comprising the reaction of at least one organic compound with at least onealkoxylating agent in the presence of a catalyst system, wherein a polyetheralcohol is obtained. The catalyst system comprises a metallo organic framework mate-rial comprising pores and at least one metal ion and at least one at least bidentate organic compound, which is coordinately bounded to said metal ion. Furthermore it relates to polyurethanes or polyurethane foams, which are obtainable by using a prepared polyether alcohol as a starting material.

Multiple Cycloadditive macrocyclization: An Efficient Method for Crown Ether-Type Cyclophanes, Bis-Calix[4]arenes and Silamacrocycles

Macrocycles constitute a broad spectrum of compounds, which play a significant role in host-guest supramolecular chemistry. We have rationally designed an efficient novel synthetic method to synthesize different types of artificial receptive macrocycles containing isoxazoline or isoxazole ring systems. This method involves multiple (double, triple or quadrupole) cycloadditions between bifunctional dipoles and bifunctional dipolarophiles. We have presented our synthetic results to show the ease with which this one-pot synthetic method can be extended to synthesize different types of macrocycles such as cyclophanes, bis-calix[4]arenes and silamacrocycles. Hence, with appropriate combination of bifunctional dipoles and bifunctional dipolarophiles, the ring size of macrocycles could be controlled. This multiple cycloadditive macrocyclization will be a useful arsenal for the synthesis of various macrocycles.

Liquid oligomers containing acrylate unsaturation

The liquid oligomeric compositions of this invention are made by the Michael addition reaction of acetoacetate functional donor compounds with multifunctional acrylate receptor compounds where the equivalent ratios of multifunctional acrylate to acetoacetate vary from >/=1:1 to >/=13.2:1 depending on the functionality of both multifunctional acrylate and acetoacetate. Unuseable gelled or solid oligomer products occur below the claimed ranges. The liquid oligomers of this invention are further crosslinked to make coatings, laminates and adhesives.