40824-67-7Relevant academic research and scientific papers
An efficient Julia olefination mediated by magnesium in ethanol
Lee, Ge Hyeong,Lee, Hyeon Kyu,Choi, Eun Bok,Kim, Bum Tae,Pak, Chwang Siek
, p. 5607 - 5608 (2007/10/02)
Reductive elimination step of Julia olefination was conveniently achieved by using magnesium powder in absolute ethanol in the presence of catalytic amount of mercuric chloride at room temperature to give the corresponding alkenes in almost quantitative yields.
Preparation of Vinylic Sulphones by Peterson Olefination using Phenyl Trimethylsilylmethyl Sulphone
Craig, Donald,Ley, Steven V.,Simpkins, Nigel S.,Whitham, Gordon H.,Prior, Michael J.
, p. 1949 - 1952 (2007/10/02)
The anion generated from phenyl trimethylsilylmethyl sulphone using butyl-lithium in dimethoxyethane, readily reacts at -78 deg C with various carbonyl compounds to afford vinylic sulphones on work-up at room temperature.The reaction conditions are tolera
