51755-92-1

Basic information

• Product Name: β-phenyl-β-hydroxyethyl phenyl sulfone
• Synonyms: β-phenyl-β-hydroxyethyl phenyl sulfone
• CAS NO: 51755-92-1
• Molecular Weight: 262.329
• Mol File: 51755-92-1.mol
• Article Data: 14

Chemical Properties

• CAS DataBase Reference: β-phenyl-β-hydroxyethyl phenyl sulfone(CAS DataBase Reference)
• NIST Chemistry Reference: β-phenyl-β-hydroxyethyl phenyl sulfone(51755-92-1)
• EPA Substance Registry System: β-phenyl-β-hydroxyethyl phenyl sulfone(51755-92-1)

Safety Data

• Hazardous Substances Data: 51755-92-1(Hazardous Substances Data)

Upstream product

• 60-12-8 2-phenylethanol 
• 6397-34-8 2-(2-phenylethylsulfanyl)aniline 
• 17376-04-4 2-phenethyl iodide 
• 100-42-5 styrene 
• 515-42-4 sodium phenylsulfonate 
• 1950-77-2 benzenesulfonyl iodide 
• 96-09-3 styrene oxide 
• 1212-08-4 S-Phenyl benzenethiosulfonate 
• 108-98-5 thiophenol 
• 67210-34-8 1-phenyl-2-phenylsulfanyl-ethanol 
• 80-17-1 benzenesufonyl hydrazide 
• 873-55-2 sodium benzenesulfonate 
• 77144-78-6 1-Benzenesulphonyl-2-iodo-2-phenylethane 
• 5418-11-1 phenyl styryl sulfone 

Downstream Products

• 16212-06-9 phenyl styryl sulfone 
• 3406-03-9 2-(phenylsulfonyl)acetophenone 
• 56107-05-2 Methanesulfonic acid 2-benzenesulfonyl-1-phenyl-ethyl ester 
• 100-42-5 styrene 
• 873-55-2 sodium benzenesulfonate 
• 27846-25-9 1-phenyl-2-(phenylsulfonyl)ethane 
• 2643-39-2 1-Benzenesulphonyl-2-bromo-2-phenylethane 
• 6461-58-1 (1-chloro-2-(phenylsulfonyl)ethyl)benzene 
• 40824-67-7 Acetic acid 2-benzenesulfonyl-1-phenyl-ethyl ester 

Relevant articles and documents

Catalyst-free oxidation of sulfides to sulfoxides and diethylamine catalyzed oxidation of sulfides to sulfones using Oxone as an oxidant

Abstract: We describe here our journey from the failure of our attempts in controlled oxidation of sulfides to sulfoxides using an Oxone–KBr combination to our success in the development of a catalyst-free protocol for the oxidation of sulfides to sulfoxides using Oxone as an oxidant. We also describe the failure of our attempts at the oxidation of sulfides to sulfones using an excess of Oxone–KBr as well as Oxone, and our success towards the development of a rapid, scalable and chromatography-free protocol for the oxidation of sulfides to sulfones using diethylamine–Oxone as an unprecedented catalyst–oxidant combination.

Visible-Light-Promoted Remote C-H Functionalization of o-Diazoniaphenyl Alkyl Sulfones

Visible-light irradiation of ortho-diazoniaphenyl alkyl sulfones in the presence of Ru(bpy)32+ results in remote Csp3-H functionalization. Key mechanistic steps in these processes involve intramolecular hydrogen atom transfer from Csp3-H bonds to aryl radicals to generate alkyl/benzyl radicals. Subsequent polar crossover occurs by single-electron oxidation of the alkyl/benzyl radicals to carbenium ions that then intercept nucleophiles. We have developed remote hydroxylations, etherifications, an amidation, and C-C bond formation processes using this strategy.