408514-86-3Relevant academic research and scientific papers
Formation and structure of tris(diphenylstibino)amine
Balazs, Lucia,Breunig, Hans Joachim,Kruger, Tamara,Lork, Enno,Breunig
, p. 1325 - 1327 (2001)
Tris(diphenylstibino)amine (Ph2Sb)3N (1) is formed in 49.5% yield by ammonolysis of Ph2SbCl in liquid NH3, and as a side product of the synthesis of Ph4Sb2 by reactions of Ph3Sb with Na and BrCH2CH2Br in liquid NH3. The structure of 1 was determined by single crystal X-ray diffraction. The crystals consist of molecules with an almost planar Sb3N core (sum of the angles at nitrogen: 352.14°).
