4088-58-8

Upstream product

• 7334-12-5 1,2-di([1,1'-biphenyl]-4-yl)diazene oxide 
• 98-80-6 phenylboronic acid 
• 586-78-7 para-nitrophenyl bromide 
• 92-93-3 1-phenyl-4-nitrobenzene 
• 92-52-4 biphenyl 
• 60-29-7 diethyl ether 

Downstream Products

• 92-69-3 4-Phenylphenol 
• 92-96-6 N,N'-bis-biphenyl-4-yl-thiourea 
• 92-67-1 4-phenylalanine 
• 5326-53-4 1,2-di([1,1'-biphenyl]-4-yl)diazene 

Relevant academic research and scientific papers

One-pot procedures for the formation of secondary aryl amines from nitro aryls

Strategies for the one-pot formation of secondary aryl amines from the corresponding nitro aryls by utilizing reductive amination procedures are discussed. The extension of this chemistry where a Suzuki-Miyaura cross-coupling is conducted between a boronic acid and bromonitrobenzene prior to the reductive amination in one-pot is also presented. Georg Thieme Verlag Stuttgart, New York.

Reductive coupling of nitroarenes to hydrazoarenes with aluminium and potassium hydroxide in methanol

A simple and inexpensive procedure for the reductive coupling of nitroarenes to hydrazoarenes with aluminium and potassium hydroxide in methanol at ambient temperature is reported. The coupling is proposed to proceed by single electron transfer from aluminium.