41096-33-7Relevant articles and documents
Iron-catalyzed oxidative addition of alkoxycarbonyl radicals to alkenes with carbazates and air
Taniguchi, Tsuyoshi,Sugiura, Yuki,Zaimoku, Hisaaki,Ishibashi, Hiroyuki
supporting information; experimental part, p. 10154 - 10157 (2011/02/24)
Clean and simple: Alkoxycarbonyl radicals generated from carbazates by iron catalysis in air underwent addition to a variety of alkenes to give the corresponding β-hydroxyesters (see scheme). The simple experimental procedure for this transformation has the added advantage that the reagents are environmentally friendly. R1,R2=alkyl, alkynyl, aryl, CO2Et; [Fe(Pc)]=iron phthalocyanine. Copyright