4115-66-6Relevant academic research and scientific papers
Mechanistic Studies in the Chemistry of Urea. Part 7. Reaction with Acetone and Mesityl Oxide
Butler, Anthony R.,Hussain, Ishtiaq
, p. 232 - 234 (2007/10/02)
By application of spectral methods it has been confirmed that the structure of the product of reaction between urea and acetone under acid conditions is (3).A mechanism for this reacton has been proposed.If acetone is replaced by mesityl oxide then the product is (7), rather than (6).A similar mechanism operates in this reaction.Analugous products are obtained with 1-methylurea, but 1,3-dimethylurea does not react under these conditions.
Reaction of BiCl3 with N,N'-Bis(trimethylsilyl)urea and Acetone
Georgiades, A.,Schilling, G.,Latscha, H. P.
, p. 709 - 711 (2007/10/02)
The reaction of BiCl3, N,N'-bis(trimethylsilyl)urea and acetone yields compound 1 with the formula C22H46Cl9N8O7Bi.After treatment of 1 with acetone /dimethylformamid the spirocompound 4,4,10,10-tetramethylspiro-1,3,7,9-tetrazaundecadion-2,8 (3) could be isolated.The structure of 3 is described and a reaction mechanismus is proposed. - Keywords: 4,4,10,10-Tetramethylspiro-1,3,7,9-tetrazadecadion-2,8-Bismuthtrichloride
