412339-56-1Relevant academic research and scientific papers
Visible-Light-Driven Iron-Promoted Thiocarboxylation of Styrenes and Acrylates with CO2
Ye, Jian-Heng,Miao, Meng,Huang, He,Yan, Si-Shun,Yin, Zhu-Bao,Zhou, Wen-Jun,Yu, Da-Gang
supporting information, p. 15416 - 15420 (2017/11/01)
The first thiocarboxylation of styrenes and acrylates with CO2 was realized by using visible light as a driving force and catalytic iron salts as promoters. A variety of important β-thioacids were obtained in high yields. This multicomponent reaction proceeds in an atom- and redox-economical manner with broad substrate scope under mild reaction conditions. Notably, high regio-, chemo-, and diasteroselectivity are observed. Mechanistic studies indicate that a radical pathway can account for the unusual regioselectivity.
