41350-71-4Relevant academic research and scientific papers
Cyclohexenylphenyldiazene: A simple surrogate of the azobenzene photochromic unit
Conti, Irene,Marchioni, Filippo,Credi, Alberto,Orlandi, Giorgio,Rosini, Goffredo,Garavelli, Marco
, p. 3198 - 3210 (2008/01/27)
We have carried out an experimental and computational study on the ground- and excited-state photochemical and photophysical properties of (1-cyclohexenyl)phenyldiazene (CPD), a species formally derived from azobenzene in which one of the phenyl rings is
α-(1-PHENYLHYDRAZINO)-ALKANONE PHENYLHYDRAZONES: THE REACTION WITH CARBONYL COMPOUNDS
Schantl, Joachim G.,Karpellus, Peter,Prean, Michael
, p. 5807 - 5814 (2007/10/02)
The unsymmetrically disubstituted hydrazines 1 were condensed with carbonyl compounds.Some of the expected condensation products were isolated, but some were formed as unstable intermediates which underwent 1,4-elimination: The phenylhydrazone of the carbonyl compound used was obtained, together with the corresponding phenylazo-alkene 11 or alternatively, the 1,4-addition product of a different protic nucleophile to 11.
