41424-73-1Relevant articles and documents
A Facile Stereoselcetive Synthesis of (E)-1-Aryl-1,2,3,3,3-pentafluoropropenes and (E)-1-Aryl-2-chloro-1,3,3,3-tetrafluoropropenes
Kuroboshi, Manabu,Hiyama, Tamejiro
, p. 1607 - 1610 (2007/10/02)
Arenecarbaldehydes ArCHO were allowed to react with a carbenoid reagent CF3CX2Mtl (X=Cl, Mtl=ZnCl, X=F, Mtl=LI) to give the adducts ArCH(OH)CX2CF3 whose hydroxyl group was substituted by fluorine.Dehydrohalogenating of the resultant ArCHFCX2CF3 (X=Cl or F
Electrophilic Bromination of Fluoro Olefins: Syn vs. Anti Addition
Naae, Douglas G.
, p. 1394 - 1401 (2007/10/02)
The ionic addition of bromine in glacial acetic acid to 4-RC6H4CF=CFX (R = CO2H, Br, H, CH3, OCH3; X = Cl, CF3) and 4-RC6H4CH=CFCl (R = Br, CH3) has been studied.For all olefins the 1,2-dibromo adduct is the predominant product, with a minor amount of the