41654-56-2Relevant academic research and scientific papers
Synthesis, crystal structure, and reactivity of (5,10,15,20-tetraphenylporphyrinato)ruthenium(II) (diethoxycarbonyl)carbene methanol
Galardon, Erwan,Le Maux, Paul,Toupet, Loic,Simonneaux, Gérard
, p. 565 - 569 (1998)
The new (porphyrin)ruthenium(II) carbene complex 1 has been prepared by treating (TPP)-Ru(CO)[EtOH] with excess diethyl diazomalonate. The good stability of this complex allowed us to determine its structure by single-crystal X-ray diffraction. The reacti
Oxidation of Ruthenium(II) and Ruthenium(III) Porphyrins. Crystal Structures of μ-Oxo-bis and Ethoxo(meso-tetraphenylporphyrinato)-(ethanol)ruthenium(III)-Bisethanol
Collman, J. P.,Barnes, C. E.,Brothers, P. J.,Collins, T. J.,Ozawa, T.,et al.
, p. 5151 - 5163 (2007/10/02)
The synthesis of a series of dinuclear Ru(IV) μ-oxo complexes2O and 2O (Por = OEP, TPP, T-n-PrP; OR = OCH3, OC2H5, p-OC6H4CH3, o-OC6H4OH; X = Br, Cl, CF3CO2, H2SO4) by tert-butyl hydroperoxide oxidation of Ru(Por)(CO)(R'OH) (R' = CH
