(meso-tetraphenylporphyrinato)carbonyl(ethanol)ruthenium(II)

Base Information

• Chemical Name: (meso-tetraphenylporphyrinato)carbonyl(ethanol)ruthenium(II)
• CAS No.: 41654-56-2
• Molecular Formula: C₄₇H₃₄N₄O₂Ru
• Molecular Weight: 787.883
• Mol file: 41654-56-2.mol

Synonyms:(meso-tetraphenylporphyrinato)carbonyl(ethanol)ruthenium(II)

Chemical Property of (meso-tetraphenylporphyrinato)carbonyl(ethanol)ruthenium(II)

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

Technology Process of (meso-tetraphenylporphyrinato)carbonyl(ethanol)ruthenium(II)

There total 5 articles about (meso-tetraphenylporphyrinato)carbonyl(ethanol)ruthenium(II) which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 89.0%

(5,10,15,20-tetraphenylporphyrinato)ruthenium(II) (diethoxycarbonyl)carbene + carbon monoxide (201230-82-2) → (meso-tetraphenylporphyrinato)carbonyl(ethanol)ruthenium(II) (41654-56-2)

Guidance literature:

In dichloromethane; CO-atmosphere; stirring (18 h);

DOI:10.1021/om970790u

Reference yield: 70.0%

5,10,15,20-tetraphenyl-21H,23H-porphine (917-23-7,20998-75-8) + ruthenium(III) chloride trihydrate (14898-67-0) → (meso-tetraphenylporphyrinato)carbonyl(ethanol)ruthenium(II) (41654-56-2)

Guidance literature:

With formaldehyd; ethanol; In water; addn. of CH2O in water to RuCl3 in EtOH, refluxing till colour pale yellow, evapn., addn. to hot stirred soln. of H2TPP in EtOH (1 h), react. for 30 h (vis.-spectroscopy); filtration, addn. of water to filtrate, pptn., filtration, washing (water), drying (vacuum), recrystn. (CH2Cl/EtOH), washing (n-hexane), drying (vacuum); elem. anal.;

DOI:10.1016/S0020-1693(00)85410-9

Reference yield:

[Ru(tetraphenylporphyrinato)(C6H5N2)acetone]BF4 + borohydride → (meso-tetraphenylporphyrinato)carbonyl(ethanol)ruthenium(II) (41654-56-2)

Guidance literature:

In ethanol; N2-atmosphere;

DOI:10.1016/S0020-1693(00)95381-7

upstream raw materials:

5,10,15,20-tetraphenyl-21H,23H-porphine

ruthenium(III) chloride trihydrate

carbon monoxide

Downstream raw materials:

carbonylpiperidinetetraphenylporphiteruthenium(II)

(meso-tetraphenylporphyrinato)bis(triethylphosphite)ruthenium(II)

Ru((C₆H₅C₅H₂N)4)((CH₃(CH₂)3)3P)2