41820-27-3Relevant academic research and scientific papers
Cross-metathesis reactions as an efficient tool in the synthesis of fluorinated cyclic β-amino acids
Fustero, Santos,Sanchez-Rosello, Maria,Acena, Jose Luis,Fernandez, Begona,Asensio, Amparo,Sanz-Cervera, Juan F.,Del Pozo, Carlos
supporting information; experimental part, p. 3414 - 3423 (2009/09/26)
The synthesis of enantiomerically pure, cyclic, γ,γ- difluorinated β-amino acids with various ring sizes has been carried out with a cross-metathesis (CM) reaction being one of the key steps, followed by a Dieckmann-type condensation to bring about the cy
METHOD FOR THE HYDRATION OF A MONOOLEFINICALLY UNSATURATED COMPOUND CARRYING AT LEAST TWO FUNCTIONAL GROUPS
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Page/Page column 9; 10, (2008/06/13)
Disclosed is a method for hydrating a monoolefinically unsaturated compound carrying at least two functional groups that are independently selected among a nitrile group, carboxylic acid group, carboxylic acid ester group, and carboxylic acid amide group, to a saturated compound carrying the same at least two functional groups in the presence of a rhodium-containing compound which acts as a catalyst and is homogeneous regarding the reaction mixture.
Ionic Liquids, 3. Synthesis and Utilisation of Protic Imidazolium Salts in Homogeneous Catalysis
Picquet, Michel,Tkatchenko, Igor,Tommasi, Immacolata,Wasserscheid, Peter,Zimmermann, Joerg
, p. 959 - 962 (2007/10/03)
Protonation of 1-alkylimidazoles provides halogen-free salts which act as ionic liquids and proton reservoir in proton- and metal-assisted catalytic processes like dimerisation of methyl acrylate and ring closing metathesis, and lead to significant improvements both in activity and selectivity.
Electrochemical reduction of CO2 in the presence of 1,3-butadiene using a hydrogen anode in a nonaqueous medium
Grinberg, V. A.,Koch, T. A.,Mazin, V. M.,Mysov, E. I.,Sterlin, S. R.
, p. 294 - 299 (2007/10/03)
The possibility or anodic generation of a solvated proton on gas-diffusion electrode in an aprotic medium in the presence of carbon dioxide and 1,3-butadiene has been demonstrated. Formic acid was shown to be the only product of the reaction in the initially approtic medium with the use of a hydrogen gas-diffusion anode. The influence of the counterion on the reactivity of the CO2*- radical anion in electrocarboxylation was shown experimentally.
