42075-46-7Relevant academic research and scientific papers
Adamantyl-Containing O-Monothioesters. II. Synthesis and Chemical Transformations of O-Methyl (1-Adamantyl)thioacetate in Reaction with Piperidine
Klimko, Yu. E.,Isaev, S. D.,Yurchenko, A. G.
, p. 166 - 170 (2007/10/02)
O-Methyl (1-adamantyl)thioacetate has been prepared for the first time by reaction of methyl (1-adamantyl)acetate with phosphorus pentasulfide in dioxane.The reaction of this product with piperidine yields corresponding S-ester, (1-adamantyl)aceto- and (1-adamantyl)thioacetopiperidides, and N-methylpiperidine.A mechanism of this reaction has been proposed, based on comparative analysis of behavior of O-methyl 1-adamantylthioacetate and its analogs, adamantane-1-thiocarboxylic and thiopivalic acid O-esters.
Reactions of In-Situ Generated Acyllithium Reagents with Carbon Disulfide and Carbonyl Sulfide.
Seyferth, Dietmar,Hui, Richard C.
, p. 2623 - 2626 (2007/10/02)
In-situ generated (at -110 deg C to -135 deg C) acyllithium reagents, RC(O)Li (R=t-Bu, n-Bu), react with CS2 to give Li with loss of CS.On the other hand, COS reacts to give Li.
