s-Methyl 2,2-dimethylpropanethioate

Base Information

Chemical Name:s-Methyl 2,2-dimethylpropanethioate
CAS No.:42075-46-7
Molecular Formula:C6H12OS
Molecular Weight:132.2239
Hs Code.:
NSC Number:133259
DSSTox Substance ID:DTXSID70299848
Nikkaji Number:J520.335J
Wikidata:Q82042530
Mol file:42075-46-7.mol

Synonyms:42075-46-7;s-methyl 2,2-dimethylpropanethioate;NSC133259;SCHEMBL1319847;DTXSID70299848;NSC-133259;2,2-Dimethylpropanethioic acid S-methyl ester

Suppliers and Price of s-Methyl 2,2-dimethylpropanethioate

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 5 raw suppliers

Chemical Property of s-Methyl 2,2-dimethylpropanethioate

Chemical Property:

Vapor Pressure:3.68mmHg at 25°C
Boiling Point:151.4°Cat760mmHg
Flash Point:39.2°C
Density:0.953g/cm³
XLogP3:2.1
Hydrogen Bond Donor Count:0
Hydrogen Bond Acceptor Count:2
Rotatable Bond Count:2
Exact Mass:132.06088618
Heavy Atom Count:8
Complexity:91.2

Purity/Quality:: 99% ^*data from raw suppliers

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:: SDS file from LookChem

Useful:

Canonical SMILES:CC(C)(C)C(=O)SC

Technology Process of s-Methyl 2,2-dimethylpropanethioate

There total 3 articles about s-Methyl 2,2-dimethylpropanethioate which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield:

: 74-93-1
methylthiol

: 3282-30-2
pivaloyl chloride

: 42075-46-7
S-methyl thiopivaloate

Guidance literature:: With pyridine; In diethyl ether;
DOI:10.1021/ja00485a030

Reference yield:

: 110-89-4
piperidine

: 138963-93-6
Thiopivalinsaeure-O-methylester

: 55581-65-2
2,2-dimethyl-1-(piperidin-1-yl)propan-1-one

: 42075-46-7
S-methyl thiopivaloate

: 2,2-Dimethyl-thiopropionic acid; compound with piperidine

Guidance literature:: at 106 ℃; for 0.5h; Title compound not separated from byproducts;

Reference yield:

: 75-15-0,12122-00-8
carbon disulfide

: 594-19-4
tert.-butyl lithium

: 74-88-4
methyl iodide

: 42075-46-7
S-methyl thiopivaloate

Guidance literature:: Yield given. Multistep reaction; 1) THF/Et₂O/pentane, -110 deg C, 30 min. 2) 2 hrs, -110 deg C to -50 deg C 3) room t.;
DOI:10.1016/S0040-4039(01)81246-6