42138-78-3Relevant academic research and scientific papers
A versatile method for the conversion of oximes to nitroalkanes
Bose, D. Subhas,Vanajatha
, p. 4531 - 4535 (1998)
A convenient oxidation of oximes to nitroalkanes has been developed using oxone in acetonitrile.
Synthesis of nitroalkanes from alkylhalides under mild and nonaqueous conditions by using polymer supported nitrites
Zarchi, Mohammad Ali Karimi,Zarei, Amin
, p. 309 - 311 (2007/10/03)
Alkyl halides are efficiently converted to their corresponding nitroalkanes under mild and nonaqueous conditions by using polymer supported nitrites. The polymeric reagent is regenerable.
SYNTHESIS, PROPERTIES, AND CRYSTAL STRUCTURE OF SILYL NITRONATES (SILYL ESTERS OF ACI-NITROALKANES): TOWARDS THE SN2 REACTION PATH WITH RETENTION OF CONFIGURATION AT SILICON
Colvin, Ernest W.,Beck, Albert K.,Bastani, Bahram,Seebach, Dieter,Kai, Yasushi,Dunitz, Jack D.
, p. 697 - 710 (2007/10/02)
An efficient and flexible method for the preparation of silyl nitronates is described (see 1-10).NMR. spectral investigations indicate a rapid 1,3-silyl migration process, with an activation energy of about 10 kcal mol-1.X-ray crystallographic
