42142-24-5

Upstream product

• 123701-34-8 N-benzyl-N,N-dimethyl-1-(trimethylsilyl)ethylammonium iodide 
• 75-16-1 methylmagnesium bromide 
• 28715-85-7 Dimethyl-(2-methyl-benzylidene)-ammonium; iodide 
• 660-68-4 diethyl amine hydrochloride 
• 577-16-2 2-Methylacetophenone 
• 529-20-4 2-methylphenyl aldehyde 
• 74-89-5 methylamine 
• 74-88-4 methyl iodide 

Downstream Products

• 344301-79-7 <α-phenyl>ethyl>dimethylamine 
• 83781-60-6 <α-ethyl>trimethylammonium iodide 
• 76463-53-1 Trimethyl-(1-{2-[3-((1S,5S)-1-methyl-2-oxo-5-vinyl-cyclopentyl)-1-trimethylsilanyl-propyl]-phenyl}-ethyl)-ammonium; iodide 
• 83781-77-5 (E,E)-α,α'-dimethyl-o-quinodimethane 
• 76463-53-1 Trimethyl-(1-{2-[3-((1S,5S)-1-methyl-2-oxo-5-vinyl-cyclopentyl)-1-trimethylsilanyl-propyl]-phenyl}-ethyl)-ammonium; iodide 
• 270578-45-5 <α-phenyl>ethyl>trimethylammonium iodide 
• 76463-47-3 <α-ethyl>dimethylamine 

Relevant academic research and scientific papers

Chemical Behavior of N-Alkyl-N-methylbenzylammonium N-Alkylide

N-Alkyl-N-methyl(4-substituted benzyl)ammonium N-alkylides (3), produced by fluoride ion induced desilylation of N-alkyl-N-methyl-N-(4-substituted benzyl)-1-(trimethylsilyl)alkylammonium iodides (2), were mainly converted into N-alkyl-N-methyl-1-(4-substituted benzyl)alkylamines (5, Stevens rearrangement products) and 4-substituted toluenes (8).Both compounds were produced via radical-forming and -destroying pathways from 2-substituted-6--5-methylene-1,3-cylohexadienes (4), which were initially formed from 3 by sigmatropic rearrangement.There is no direct migration pathway from 3 to 5.