42747-41-1

Upstream product

• 39776-34-6 3-chloro-2,5,5-trimethyl-cyclohex-2-enone 
• 52898-23-4 γ,δ-epoxy-eucarvone 
• 917-64-6 methyl magnesium iodide 
• 42117-32-8 2-methoxy-4,4-dimethylcyclohex-2-en-1-one 
• 1125-11-7 methyldimedone 
• 36269-88-2 2,6,6-trimethyl-2,3-epoxycyclohept-4-ene-1-one 

Downstream Products

• 33543-18-9 2,5,5-trimethylcyclohexanone 
• 79918-74-4 cis-(1S,2R)-2,5,5-trimethylcyclohexanol 
• 79918-73-3 (R)-(+)-2,5,5-trimethylcyclohexanone 
• 53823-07-7 (+/-)-Africanol 
• 53823-07-7 9-epi-africanol 
• 107197-13-7 trans-(tetramethyl-2,3,5,5-cyclohexanone-2yl)-3-acrylate de methyle Δ² trans 

Relevant academic research and scientific papers

1?,?*-Induced Photocleavage of γ,δ-Epoxy-eucarvone

On 1?,Π*-excitation 1 undergoes cleavage of the C,C-oxirane bond (1 -> c) and isomerizes to the bicyclic dihydrofurane compound 5.In addition, 1 shows photocleavage of the C(γ),O-oxirane bond (1 -> d) and gives the isomers 2, 3, 6, 7 and 8.Furthermore, the cyclohexenone 9 and the cyclohexene-1,4-dione formed presumably via an intermediate 13, which could also arise from d.Besides these products the compounds 11 and 12 are obtained, which are photoproducts of 2.