4281-67-8

Basic information

• Product Name: cyclohexyl diphenyl phosphate
• Synonyms: Cyclohexyl diphenyl phosphate; phosphoric acid, cyclohexyl diphenyl ester
• CAS NO: 4281-67-8
• Molecular Formula: C₁₈H₂₁O₄P
• Molecular Weight: 332.3307
• Mol File: 4281-67-8.mol
• Article Data: 19

Chemical Properties

• Boiling Point: 409.4°C at 760 mmHg
• Flash Point: 214.9°C
• Density: 1.21g/cm³
• Vapor Pressure: 1.54E-06mmHg at 25°C
• Refractive Index: 1.562
• CAS DataBase Reference: cyclohexyl diphenyl phosphate(CAS DataBase Reference)
• NIST Chemistry Reference: cyclohexyl diphenyl phosphate(4281-67-8)
• EPA Substance Registry System: cyclohexyl diphenyl phosphate(4281-67-8)

Safety Data

• Hazardous Substances Data: 4281-67-8(Hazardous Substances Data)

Upstream product

• 108-95-2 phenol 
• 26386-88-9 diphenyl phosphoryl azide 
• 108-93-0 cyclohexanol 
• 2524-64-3 chlorophosphoric acid diphenyl ester 
• 838-85-7 diphenyl hydrogen phosphate 
• 681035-22-3 (2-oxo-5,5-diphenyl-oxazolidin-3-yl)-phosphonic acid diphenyl ester 
• 449813-82-5 3-(diphenylphosphono)-2-(N-cyanoimino)thiazolidine 

Downstream Products

• 50585-08-5 (cyclohexylmethylene)dibenzene 
• 4281-59-8 Cyclohexyl-α-glyceryl-hydrogenphosphat 
• 4281-58-7 Cyclohexyl-<2-hydroxy-2-methyl-propyl>-phosphat 
• 4281-61-2 Cyclohexyl-<2-hydroxy-1-methyl-propyl>-phosphat 
• 4281-60-1 Cyclohexyl-<2-hydroxy-1,1-dimethyl-ethyl>-phosphat 
• 4281-57-6 Cyclohexyl-<2-hydroxy-propyl>-hydrogen-phosphat 
• 4281-56-5 Cyclohexyl-glycolyl-hydrogen-phosphat 
• 1623-22-9 cyclohexyl dihydrogen phosphate 
• 838-85-7 diphenyl hydrogen phosphate 
• 110-83-8 cyclohexene 

Relevant articles and documents

Zinc-catalyzed transformation of diarylphosphoryl azides to diarylphosphate esters and amides

We have developed a facile and efficient procedure for the synthesis of diarylphosphate esters and amides. Using Zn(acac)2 as the catalyst, the reaction of diarylphosphoryl azides with aliphatic alcohols and phenols through an unusual P?N bond cleavage provided a number of diarylphosphate esters in good yields (22 examples, up to 94%). Additionally, various diarylphosphate amides were obtained from the corresponding amines in excellent yields as well (8 examples, up to 96%).

Method for catalytically synthesizing phosphoric acid mixed ester compound by using chitosan-loaded copper

The invention relates to a method for synthesizing a phosphoric acid mixed ester compound under the catalysis of chitosan-loaded copper. The preparation method comprises the following steps of: sequentially adding an azido phosphate compound, a chitosan-l

Copper catalyzed synthesis of aryl/alkyl mixed phosphates from diphenylphosphoryl azides and aliphatic alcohols under mild conditions

An efficient and convenient one-pot protocol is developed to prepare aryl/alkyl mixed phosphates in the presence of copper catalyst under exceptionally mild conditions. A series of versatile, ubiquitous, and inexpensive phosphoryl azides and aliphatic alcohols are combined for the first time ever. Diphenylphosphoryl azide is employed as novel phosphors reagent through an unexpected cleavage of P[sbnd]N bond. The transformation is advantageous with respect to a broad of functional group compatibility and different esterification products are isolated in good to excellent results. This new catalytic system represents a superior platform towards a mild, operationally simple, practical, and scalability alternative to access target molecules. Furthermore, a plausible mechanism is proposed based on insightful mechanistic studies.