42846-29-7

Upstream product

• 2816-57-1 2,6-dimethylcyclohexanone 
• 576-26-1 2.6-dimethylphenol 
• 39170-84-8 cis,cis-2,6-dimethylcyclohexanol 
• 42846-29-7 trans,trans-2,6-dimethylcyclohexanol 
• 6850-63-1 cis,trans-2,6-dimethylcyclohexylamine 
• 766-43-8 trans-2,6-dimethylcyclohexanone 
• 766-42-7 cis-2,6-dimethylcyclohexanone 

Downstream Products

• 766-42-7 cis-2,6-dimethylcyclohexanone 
• 766-43-8 trans-2,6-dimethylcyclohexanone 
• 78414-96-7 r-1-methoxy-t-2,t-6-dimethylcyclohexane 
• 42846-29-7 (1r*,2R*,6S*)-2,6-dimethylcyclohexanol 

Relevant academic research and scientific papers

ORGANIC COMPOUND USED AS FRAGRANCE INGREDIENTS

A compound of formula I wherein R1, R2, R3 and R4 can be independently selected from H or Me, n ＝ 0, 1, the dotted lines are indicating single bonds, or in case n ＝ 0 an isolated double bond at position 3', or in case n ＝ 1 an isolated double bond at position 3' or 4', and the wavy bond is indicating an unspecified configuration of the adjacent double bond. Said compounds, as well as precursors capable to generate said compounds, are useful as fragrance ingredients.

Differential potency of 2,6-dimethylcyclohexanol isomers for positive modulation of GABAA receptor currents

GABAA receptors meet all of the pharmacological requirements necessary to be considered important targets for the action of general anesthetic agents in the mammalian brain. In the following patch-clamp study, the relative modulatory effects of

Observations on the stereochemistry of reduction of 2,6- dimethylcyclohexanones

The reduction of cis-2,6-dimethylcyclohexanone with NaBH4 in methanol is shown to produce predominantly the axial alcohol, an unexpected result based upon prior reports and current paradigms for similar cyclohexanone reductions. This finding pr

Activation of Reducing Agents. Sodium Hydride Containing Complex Reducing Agents. 36. Stereoselective Reduction of Alkylcyclohexanones and Rigid Ketones by MCRA's

The stereoselectivity of reduction of selected ketones by a variety of Complex Reducing Agents (resulting from the Aggregative Activation of NaH and symbolized MCRA's) has been investigated.The stereochemistry of reduction is shown to be dependent on the nature of the metal.Steric hindrance plays an important role and the apparent size of the reagents follows the trend MnCRA's > ZnCRA's, CdCRA's > NiCRA's, CoCRA's.On the other hand NiCRA's and CoCRA's have been found as very strong isomerizing reagents.Insertion of the metal species into the C-O bond with formation of metallacycles appears as one of the possible mechanisms intervening during the reduction of ketones by MCRA's.

Activation of Reducing Agents. Sodium Hydride Containing Complex Reducing Agents. 13. Selective Heterogeneous Hydrogenation of Polyfunctional Substrates over Nic

Preparative-scale heterogeneous hydrogenation over Nic at room temperature and 1 atm are described.It is shown that these catalysts allow the selective hydrogenation of carbon-carbon double bonds in the presence of oxo groups without side reactions.Alkynes and functional alkynes are selectively hydrogenated to the corresponding cis alkenes in high yields.Carbonyl group hydrogenations were also performed in high yields.Selective hydrogenation properties of Nic were exemplified in the steroid series.Finally, it was demonstrated that this new catalyst-preparation concept is not limited to nickel and also applies to the preparation of cobalt and palladium catalysts.