43058-55-5Relevant articles and documents
Allylic Carbonates. Efficient Allylating Agents of Carbonucleophiles in Palladium-Catalyzed Reactions under Neutral Conditions
Tsuji, Jiro,Shimizu, Isao,Minami, Ichiro,Ohashi, Yukihiro,Sugiura, Teruo,Takahashi, Kazuhiko
, p. 1523 - 1529 (2007/10/02)
Allylation of β-keto esters or malonates was carried out in good yields under neutral conditions by using allylic carbonates in the presence of palladium-phospine catalyst.Although simple ketones, esters, nitriles, and sulfones hardly react with allylic carbonates, α-alkenyl or α-aryl ketones, esters, nitriles, and sulfones were also allylated by using palladium-bis(diphenylphosphino)ethane catalyst under neutral conditions.