433305-07-8

Upstream product

• 108-05-4 vinyl acetate 
• 14365-32-3 trans-2-fluorocyclohexanol 
• 75-36-5 acetyl chloride 
• 108-24-7 acetic anhydride 
• 110-83-8 cyclohexene 
• 78948-09-1 acetyl hypofluorite 
• 110-82-7 cyclohexane 
• 35998-47-1 acetic acid-(2-chloro-cyclohexyl ester) 

Relevant academic research and scientific papers

Conformational properties of trans-2-halo-acetoxycyclohexanes: 1H NMR, solvation and theoretical investigation

Conformational analyses of trans-2-halo-acetoxycyclohexanes have been performed through NMR, theoretical calculations and solvation theory. The solvent dependence of coupling constants analysed together with solvation parameters of the main calculated geo

Synthesis of optically active vicinal fluorohydrins by lipase-catalyzed deracemization

Three microbial lipases have been used to deracemize trans-2-fluorocycloalkanols 2 both by hydrolysis of the corresponding acetates 3 or chloroacetates 4 and by esterification of the fluorohydrins 2 using vinyl acetate and vinyl chloroacetate, respectivel

Mechanistic aspects of the fluorination of cyclohexane and cyclohexene with acetyl hypofluorite in acetic acid

The reaction of acetyl hypofluorite in acetic acid with both cyclohexane and cyclohexene has been investigated.Analysis by GCMS and radio-HPLC, using (18)F as a tracer, revealed that apart from typical products expected from a radical reaction, several compounds originating from carbocationic intermediates were formed.On the basis of the observed products, a single-electrontransfer (SET) mechanism leading to an intermediate radical-cation is proposed.

Electrophilic Fluorination of Unsaturated Systems with the Recently Developed Acetyl Hypofluorite

Acetyl hypofluorite (AcOF, 1) is a relatively new reagent which is prepared in situ from F2 and is an excellent source for electrophilic fluorine.Unlike the other known fluoroxy reagents, it reacts smoothly and quickly at -78 deg C with many types of olef