434-84-4Relevant articles and documents
Electrolysis at an Anthracene Crystal/Aqueous NO3- Solution Interface: The Role of Crystal Defects
Pope, M.,Mao, B.,Steigman, J.,Geacintov, N. E.
, p. 1719 - 1720 (1990)
The electrolysis of a 1 M solution of NaNO3 by means of an anthracene crystal electrode results in the production of many surface reaction products, including 9-nitroanthracene (9NA), bianthronyl (BA), and anthraquinone (AQ).The production of 9NA and BA have been shown to depend on the square of the current density.This dependence was rationalized by hypothesizing the need for the simultaneous discharge of two carriers at adjoining lattice defect sites.By annealing the crystals, it was found that the efficiency of producing 9NA was reduced by a factor of as much as 6; this supports the hypothesis.
Direct Exploitation of the Ethynyl Moiety in Calcium Carbide Through Sealed Ball Milling
Hosseini, Abolfazl,Schreiner, Peter R.
, p. 4339 - 4346 (2020/07/04)
Ball milling of calcium carbide (CaC2) enables the reaction of its ethynyl moiety with organic electrophiles. This was realized simply by co-milling CaC2 with organic substrates in a sealed jar without the need for an additive or a catalyst. Various ketones including those bearing α-hydrogens were ethynylated in good yields at short reaction times. Aryl halides are also amenable substrates for this protocol as they furnish aryl ethynes through a benzyne intermediate. This method offers a practical and cheap alternative to the established procedures for introducing ethynyl functionalities.
Oxidative-substitution reactions of polycyclic aromatic hydrocarbons with iodine(III) sulfonate reagents
Koser, Gerald F.,Telu, Sanjay,Laali, Kenneth K.
, p. 7011 - 7015 (2007/10/03)
Polycyclic aromatic hydrocarbons (PAH) undergo regioselective oxidative-substitution reactions with iodine(III) sulfonate reagents in dichloromethane to give the corresponding aryl sulfonate esters. The use of [hydroxy(tosyloxy)iodo]benzene in conjunction
Sc(OTf)3- and TfOH-catalyzed baeyer-villiger oxidation of carbonyl compounds with m-chloroperbenzoic acid
Kotsuki, Hiyoshizo,Arimura, Koji,Araki, Tomohiro,Shinohara, Toshio
, p. 462 - 464 (2007/10/03)
An efficient method for Baeyer-Villiger oxidation of carbonyl compounds to the. corresponding esters/lactones has been developed using m-chloroperbenzoic acid in the presence of a catalytic amount of Sc(OTf)3 or TfOH. Thieme Stuttgart.