4356-79-0

Basic information

• Product Name: methyl 6-O-acetyl-2,3,4-tri-O-benzyl-β-D-glucopyranoside
• Synonyms: methyl 6-O-acetyl-2,3,4-tri-O-benzyl-β-D-glucopyranoside
• CAS NO: 4356-79-0
• Molecular Weight: 506.596
• Mol File: 4356-79-0.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: methyl 6-O-acetyl-2,3,4-tri-O-benzyl-β-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 6-O-acetyl-2,3,4-tri-O-benzyl-β-D-glucopyranoside(4356-79-0)
• EPA Substance Registry System: methyl 6-O-acetyl-2,3,4-tri-O-benzyl-β-D-glucopyranoside(4356-79-0)

Safety Data

• Hazardous Substances Data: 4356-79-0(Hazardous Substances Data)

Upstream product

• 4356-80-3 methyl 2,3,4-tri-O-benzyl-β-D-glucopyranoside 
• 529493-92-3 2-(acetoxymethyl)-6-bromotetrahydro-2H-pyran-3,4,5-triyl triacetate 
• 100-39-0 benzyl bromide 
• 6988-40-5 methyl 2,3-di-O-benzyl-β-D-glucopyranoside 
• 100-44-7 benzyl chloride 
• 67412-01-5 Methyl 6-O-triphenylmethyl-β-D-glucopyranoside 
• 709-50-2 methyl beta-D-glucopyranoside 
• 67583-56-6 Methyl 2,3,4-O-tri-O-benzyl-6-O-triphenylmethyl-β-D-glucopyranoside 
• 13035-24-0 methyl 2,3-di-O-benzyl-4,6-O-benzylidene-β-D-glucopyranoside 
• 19488-61-0 methyl 2,3,4,6-tetra-O-benzyl α-D-glucopyranoside 
• 108-24-7 acetic anhydride 

Downstream Products

• 82231-38-7 methyl 6-O-acetyl-2,3,4-tri-O-benzyl-α-D-glucopyranoside 
• 20771-12-4 methyl 6-O-acetyl-β-D-glucopyranoside 
• 51897-71-3 4-O-acetyl-methyl β-D-glucopyranoside 

Relevant articles and documents

H-bonding activation in highly regioselective acetylation of diols

H-bonding activation in the regioselective acetylation of vicinal and 1,3-diols is presented. Herein, the acetylation of the hydroxyl group with acetic anhydride can be activated by the formation of H-bonds between the hydroxyl group and anions. The reaction exhibits high regioselectivity when a catalytic amount of tetrabutylammonium acetate is employed. Mechanistic studies indicated that acetate anion forms dual H-bonding complexes with the diol, which facilitates the subsequent regioselective monoacetylation.

Selective 6-O-Debenzylation of mono- and disaccharide derivatives using ZnCl2-Ac2O-HOAc

Freshly fused ZnCl2 in Ac2O/HOAc at room temperature has been used for 6-O-debenzylation of mono- and disaccharide derivatives giving yields more than 80%. Notably, allyl, acetyl, benzoyl, tosyl, thiono groups are unaffected under th

The function of the 5-hydroxymethyl group of lactose in enzymatic hydrolysis with beta-galactosidase from E. coli.

A series of 6-substituted methyl lactoside derivatives together with methyl allolactoside and (6S)-methyl [6-2H]lactoside have been synthesized and characterized by NMR spectroscopy. All compounds were tested as substrates for the enzyme beta-galactosidas