82231-38-7

Basic information

• Product Name: methyl 6-O-acetyl-2,3,4-tri-O-benzyl-α-D-glucopyranoside
• Synonyms: methyl 6-O-acetyl-2,3,4-tri-O-benzyl-α-D-glucopyranoside
• CAS NO: 82231-38-7
• Molecular Weight: 506.596
• Mol File: 82231-38-7.mol
• Article Data: 22

Chemical Properties

• CAS DataBase Reference: methyl 6-O-acetyl-2,3,4-tri-O-benzyl-α-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: methyl 6-O-acetyl-2,3,4-tri-O-benzyl-α-D-glucopyranoside(82231-38-7)
• EPA Substance Registry System: methyl 6-O-acetyl-2,3,4-tri-O-benzyl-α-D-glucopyranoside(82231-38-7)

Safety Data

• Hazardous Substances Data: 82231-38-7(Hazardous Substances Data)

Upstream product

• 4356-79-0 methyl 6-O-acetyl-2,3,4-tri-O-benzyl-β-D-glucopyranoside 
• 166592-73-0 methyl 2,3,4-tri-O-benzyl-6-O-(tert-butyldimethylsilyl)-α-D-glucopyranoside 
• 53008-65-4 methyl 2,3,4-tri-O-benzyl-D-glucopyranoside 
• 108-22-5 Isopropenyl acetate 
• 3879-79-6 methyl 2,3,4,6-tetra-O-benzyl-α-D-glucopyranoside 
• 97-30-3 methyl-alpha-D-glucopyranoside 
• 100-39-0 benzyl bromide 
• 50-78-2 aspirin 
• 32934-24-0 ethyl 2,3,4,6-tetra-O-acetyl-1-thio-β-D-glucopyranoside 
• 13992-16-0 (2R,3R,4S,5R,6S)-2-(acetoxymethyl)-6-(phenylthio)tetrahydro-2H-pyran-3,4,5-triyl triacetate 
• 6988-40-5 methyl 2,3-di-O-benzyl-β-D-glucopyranoside 
• 100-44-7 benzyl chloride 
• 4356-80-3 methyl 2,3,4-tri-O-benzyl-β-D-glucopyranoside 
• 7177-79-9 methyl 2,3-O-dibenzyl-4,6-O-benzylidene-α-D-glucopyranoside 

Downstream Products

• 72471-11-5 methyl 6-deoxy-6-amino-2,3,4-tri-O-benzyl-α-D-glucopyranoside 
• 674302-87-5 methyl 2,3,4-tri-O-benzyl-6-deoxy-6-(4,5,6,7-tetrachlorophthalimid-2-yl)-α-D-glucopyranoside 
• 674302-90-0 methyl 2,3,4-tri-O-benzyl-6-deoxy-6-[N-(2',3',4',6'-tetra-O-acetyl-β-D-glucopyranosyl)ureido]-α-D-glucopyranoside 
• 1378999-61-1 2',3',4'-tri-O-benzyl-6'-O-[4-(toluene-4-sulfonylamino)benzoyl]-α-D-methylglucoside 
• 1378999-57-5 2',3',4'-tri-O-benzyl-6'-O-phenylacetyl-α-D-methylglucoside 
• 4064-06-6 1,2:3,4-di-O-isopropylidene-α-D-galactopyranose 
• 4860-78-0 6-O-acetyl-1,2:3,4-di-O-isopropylidene-α-D-galactopyranose 
• 194410-26-9 3-(6'-O-acetyl-2',3',4'-tri-O-benzyl-α-D-glucopyranosyl)-1-propene 
• 314753-99-6 methyl 2,3,4-tri-O-benzyl-6-O-[2-(2,3,4,6-tetra-O-benzyl-β-D-glucopyranosylthio)prop-2-yl]-α-D-glucopyranoside 
• 61474-61-1 methyl 2,3,4-tri-O-benzyl-6-O-(2,3,4,6-tetra-O-benzyl-D-glucopyranosyl)-α-D-glucopyranoside 
• 139608-09-6 methyl 2,3,4-tri-O-benzyl-6-O-(propen-2-yl)-α-D-glucopyranoside 
• 53008-65-4 methyl 2,3,4-tri-O-benzyl-D-glucopyranoside 

Relevant articles and documents

Cyclodextrin chemistry; Part I. Application of a regioselective acetolysis method for benzyl ethers

Regioselective acetolysis of cyclomaltohexaose perbenzyl ethers at C-6 with acetic anhydride in the presence of trimethylsilyl trifluoromethanesulfonate at low temperature constitutes an easy route to the C-6 acetylated intermediate 2. Futher transformati

KMnO4-catalyzed chemoselective deprotection of acetate and controllable deacetylation-oxidation in one pot

A novel and efficient protocol for chemoselective deacetylation under ambient conditions was developed using catalytic KMnO4. The stoichiometric use of KMnO4 highlighted the dual role of a heterogeneous oxidant enabling direct access to aromatic aldehydes in one-pot sequential deacetylation-oxidation. The reaction employed an alternative solvent system and allowed the clean transformation of benzyl acetate to sensitive aldehyde in a single step while preventing over-oxidation to acids. Use of inexpensive and readily accessible KMnO4 as an environmentally benign reagent and the ease of the reaction operation were particularly attractive, and enabled the controlled oxidation and facile cleavage of acetate in a preceding step. This journal is

Isopropenyl acetate: A cheap and general acylating agent of alcohols under metal-free conditions

Functionalized primary, secondary and tertiary alcohols are efficiently acetylated by isopropenyl acetate and catalytic p-TsOH.