4360-51-4

Basic information

• Product Name: cinnamylamine
• Synonyms: cinnamylamine;styrylmethylamine;3-phenyl-2-propene-1-ylaMine
• CAS NO: 4360-51-4
• Molecular Formula: C₉H₁₁N
• Molecular Weight: 133.1903
• Mol File: 4360-51-4.mol
• Article Data: 91

Chemical Properties

• Boiling Point: 253.6°Cat760mmHg
• Flash Point: 105.4°C
• Appearance: /
• Density: 0.993g/cm³
• Vapor Pressure: 0.0181mmHg at 25°C
• Refractive Index: 1.596
• CAS DataBase Reference: cinnamylamine(CAS DataBase Reference)
• NIST Chemistry Reference: cinnamylamine(4360-51-4)
• EPA Substance Registry System: cinnamylamine(4360-51-4)

Safety Data

• Hazardous Substances Data: 4360-51-4(Hazardous Substances Data)

Usage

Synthesis Reference(s)

Synthesis, p. 941, 1984 DOI: 10.1055/s-1984-31028Tetrahedron Letters, 27, p. 1423, 1986 DOI: 10.1016/S0040-4039(00)84275-6

InChI:InChI=1/C9H11N/c10-8-4-7-9-5-2-1-3-6-9/h1-7H,8,10H2/b7-4+

Upstream product

• 22610-18-0 2-phenylazetidine 
• 4392-24-9 Cinnamyl bromide 
• 17480-07-8 2-[(E)-3-phenylprop-2-enyl]-2,3-dihydro-1H-isoindole-1,3-dione 
• 59428-70-5 N-Cinnamyltrifluoroacetamide 
• 146039-13-6 (E)-3-Phenyl-allyl-phosphorimidic acid triethyl ester 
• 4360-47-8 cinnamonitrile 
• 4393-06-0 1-Phenyl-2-propen-1-ol 
• 104-54-1 3-Phenylpropenol 
• 108-86-1 bromobenzene 
• 4510-34-3 (Z)-cinnamyl alcohol 
• 4407-36-7 (2E)-3-phenyl-2-propen-1-ol 
• 4187-87-5 1-Phenyl-2-propyn-1-ol 
• 57294-86-7 (E)-cinnamyl azide 
• 591-49-1 1-methylcyclohex-1-ene 

Downstream Products

• 75606-32-5 2-((E)-3-Phenyl-allylamino)-ethanethiol 
• 67154-89-6 1,1,1,3,3,3-Hexamethyl-2-((E)-styryl)-disilazane 
• 99510-72-2 trans-N-(3-phenylallyl)phenanthrene-9,10-dicarboximide 
• 120990-23-0 N-(phenylmethylidene)-N-[(E)-3-phenylprop-2-enyl]amine 
• 59336-59-3 cinnamaldehyde oxime 
• 1885-38-7 cinnamic nitrile 
• 5848-57-7 4-methyl-N-[(2E)-3-phenylprop-2-en-1-yl]benzene-1-sulfonamide 
• 492435-14-0 (S)-2-Hydroxy-2-phenyl-N-((E)-3-phenyl-allyl)-acetamide 
• 908351-76-8 ((S)-5-Benzyloxycarbonylamino-6-hydroxy-6-{5-[4-((E)-3-phenyl-allylcarbamoyl)-benzyl]-[1,2,4]oxadiazol-3-yl}-hexyl)-carbamic acid tert-butyl ester 
• 114675-85-3 C₁₅H₁₂N₂O₂S 
• 114675-84-2 C₁₅H₁₂N₂O₂S 

Relevant articles and documents

Charge Transport between Coupling Colloidal Perovskite Quantum Dots Assisted by Functional Conjugated Ligands

Long alkyl-chain capping ligands are indispensable for preparing stable colloidal quantum dots. However, its insulating feature blocks efficient carrier transport among QDs, leading to inferior performance in light-emitting diodes (LEDs). The trade-off between conductivity and colloidal stability of QDs has now been overcome. Methylamine lead bromide (MAPbBr3) QDs with a conjugated alkyl-amine, 3-phenyl-2-propen-1-amine (PPA), as ligands were prepared. Owing to electron cloud overlapping and the delocalization effect of conjugated molecules, the conductivity and carrier mobility of PPA-QDs films increased almost 22 times over that of OA-QD films without compromising colloidal stability and photoluminescence. PPA-QDs LEDs exhibit a maximum current efficiency of 9.08 cd A?1, which is 8 times of that of OA-QDs LEDs (1.14 cd A?1). This work provides critical solution for the poor conductivity of QDs in applications of energy-related devices.

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Monosubstituted ureas are important scaffolds in organic chemistry. They appear in various biologically active compounds and serve as versatile precursors in synthesis. Monosubstituted ureas were originally prepared using toxic and hazardous phosgene equivalents. Modern methods include transamidation of urea and nucleophilic addition to cyanate salts, both of which suffer from a narrow substrate scope due to the need for a strong acid and prolonged reaction times. We hereby report that ammonium chloride can promote the reaction between amines and potassium cyanate to generate monosubstituted ureas in water. This method proceeds rapidly under microwave irradiation and tolerates a broad range of functional groups. Unlike previous strategies, it is compatible with other nucleophiles, acid-labile moieties, and most of the common protecting groups. The products precipitate out of solution, allowing facile isolation without column chromatography.