4380-32-9

Upstream product

• 6784-45-8 (2E,6E)-farnesyl chloride 
• 142-50-7 (R)-(-)-trans-nerolidol 
• 59905-15-6 dehydronerolidol 
• 2387-68-0 3,7,11-trimethyl-6,10-dodecadien-1-yn-3-ol 
• 40716-66-3 (E)-3,7,11-trimethyl-1,6,10-dodecatrien-3-ol 
• 56194-28-6 3,7,11-trimethyl-2ξ,6E,10-dodecatrien-1-ol 

Downstream Products

• 20479-23-6 2-sesquicarene 
• 107259-72-3 (S)-3,3,3-Trifluoro-2-methoxy-2-phenyl-propionic acid (1S,2R)-5,5-dimethyl-2-(5-methyl-1-methylene-hex-4-enyl)-cyclohexyl ester 
• 107259-72-3 (S)-3,3,3-Trifluoro-2-methoxy-2-phenyl-propionic acid (1R,2R)-5,5-dimethyl-2-(5-methyl-1-methylene-hex-4-enyl)-cyclohexyl ester 
• 107259-73-4 (S)-3,3,3-Trifluoro-2-methoxy-2-phenyl-propionic acid 2-((Z)-1,5-dimethyl-hexa-1,4-dienyl)-5,5-dimethyl-cyclohexyl ester 
• 104764-30-9 2-((Z)-1,5-Dimethyl-hexa-1,4-dienyl)-5,5-dimethyl-cyclohexanol 
• 104746-49-8 (1S,2R)-5,5-dimethyl-2-(6-methylhepta-1,5-dien-2-yl)cyclohexanol 

Relevant academic research and scientific papers

PRODUCTION OF FARNESOL

The present invention relates to an improved way for the production of farnesol.

(2E, 6E) enriching [...] -

PROBLEM TO BE SOLVED: To provide a method for producing (2E, 6E)-farnesal useful as an intermediate for the production of a polyisoprenoid derivative useful as an anticancer agent.SOLUTION: The method for producing (2E, 6E)-farnesal includes heating (2Z, 6E)-farnesal in the presence of a piperidin-1-oxyl compound represented by formula (1) [wherein Ris a hydrogen atom; Ris a hydrogen atom, cyano, carboxy, isothiocyanato, maleimide, phosphate group, -OR' group or -NHR group (wherein R' is a hydrogen atom, 1-4C alkyl, acyl or 1-4C alkanesulfonyl; R is a hydrogen atom, acetyl or haloacetyl); or Rand Rtogether form an oxo group].

Bis (acetylacetonate) Dioxothiazolidine molybdenum (VI) using the method of manufacturing a [...]

PROBLEM TO BE SOLVED: To provide a method for producing farnesal useful as an intermediate for the production of a medicine, an agrochemical and perfume.SOLUTION: A method for producing farnesal represented by formula (2) includes reacting (E)-nerolidol represented by formula (1) with an oxidizing agent in the presence of bis(acetylacetonato)dioxomolybdenum(VI).

Bis (acetylacetonate) oxocarboxylic vanadium (IV) [...] manufacturing method using the same

PROBLEM TO BE SOLVED: To provide a method for producing farnesal useful as an intermediate for the production of a medicine, an agrochemical and perfume.SOLUTION: A method for producing farnesal represented by formula (2) includes reacting (E)-nerolidol represented by formula (1) with an oxidizing agent in the presence of a piperidin-1-oxyl compound and/or a sulfoxide using bis(acetylacetonato)oxovanadium(IV) and an oxidizing agent.

METHOD FOR PRODUCING FARNESAL USING VANADIUM COMPLEX

The present invention provides a method for producing farnesal that is useful as a production intermediate of pharmaceuticals, agricultural chemicals and perfumes. More specifically, the present invention provides a method for producing farnesal (3), comp

Iron-catalyzed aerobic oxidation of allylic alcohols: The issue of C=C bond isomerization

An aerobic oxidation of allylic alcohols using Fe(NO3) 3·9H2O/TEMPO/NaCl as catalysts under atmospheric pressure of oxygen at room temperature was developed. This eco-friendly and mild protocol provides a convenient pathway to the synthesis of stereodefined α,β-unsaturated enals or enones with the retention of the C-C double-bond configuration.

A Convenient Method for Conversion of Allylic Chlorides to α,β-Unsaturated Aldehydes

Tertiary amine N-oxides were found to be effective for converting chlorides to aα,β-unsaturated aldehydes.