4381-30-0Relevant academic research and scientific papers
Ligand-promoted ruthenium-catalyzed: Meta C-H chlorination of arenes using N -chloro-2,10-camphorsultam
Fan, Zhoulong,Lu, Heng,Cheng, Zhen,Zhang, Ao
supporting information, p. 6008 - 6011 (2018/06/18)
A practical meta C-H chlorination protocol is established via a Ru(0)-catalyzed ortho-metalation strategy. The use of N-chloro-2,10-camphorsultam as a new chlorinating agent is crucial for the success of the current reaction and an N-heterocyclic carbene (NHC) ligand could significantly enhance the reactivity of the catalytic transformation. The mechanistic studies reveal that an unusual ortho C-H ruthenation relay process with ortho chlorination of the C-Ru bond is probably involved.
Arylmethyl chlorides: New bifunctional reagents for palladium-catalyzed ortho -chlorination and acylation of 2-arylpyridines
Zhang, Guodong,Sun, Suyan,Yang, Fan,Zhang, Qian,Kang, Jianxun,Wu, Yusheng,Wu, Yangjie
, p. 443 - 450 (2015/02/19)
A chemoselective, palladium-catalyzed, ligand-directed ortho-C-H chlorination and acylation process has been developed, exhibiting high regioselectivity for 2-arylpyridines bearing a meta-substituent. Worthy of note is the fact that arylmethyl chlorides a
The Reactions of Superoxide Ion with Arylhydrazines
Crank, George,Gately, Garry E.,Makin, Mohammad I. H.
, p. 2499 - 2507 (2007/10/02)
Arylhydrazines react with potassium superoxide to give a variety of products, most of which are derived from interaction of aryl radicals with the solvent.Phenylhydrazine in toluene gives three isomeric metylbiphenyls, diphenylmethane and bibenzyl.In pyridine, the products identified were 2-, 3-, and 4-phenylpyridine.A more complex range of products was obtained from substituted phenylhydrazines.Products are consistent with a process in which superoxide ion abstracts hydrogen atoms from the hydrazines giving radical intermediates, including aryl radicals, which react with the solvents.
