4381-32-2Relevant articles and documents
Light-promoted C-Cl bond-forming reductive elimination of a metal-metal bonded PdIII-PdIIIcomplex
Gogoi, Kuldeep,Park, Kiyoung,Shin, Jeongcheol
, p. 7673 - 7676 (2021)
The excited-state reductive elimination (RE) activities of a metal-metal bonded PdIII2complex, [(2-phenylpyridyl)Pd(μ-acetate)Cl]2, are described. The C-Cl bond-forming RE reaction is accelerated by up to five orders of magnitude upon visible p
Tris-NHC-propagated self-supported polymer-based Pd catalysts for heterogeneous C-H functionalization
Choudhury, Joyanta,Dutta, Tapas Kumar,Mandal, Tanmoy,Mohanty, Sunit
supporting information, p. 10182 - 10185 (2021/10/12)
Three-dimensionally propagated imidazolium-containing mesoporous coordination polymer and organic polymer-based platforms were successfully exploited to develop single-site heterogenized Pd-NHC catalysts for oxidative arene/heteroarene C-H functionalization reactions. The catalysts were efficient in directed arene halogenation, and nondirected arene and heteroarene arylation reactions. High catalytic activity, excellent heterogeneity and recyclability were offered by these systems making them promising candidates in the area of heterogeneous C-H functionalization, where efficient catalysts are still scarce.
Salen-based hypercrosslinked polymer-supported Pd as an efficient and recyclable catalyst for C-H halogenation
Meng, Di,Bi, Jiajun,Dong, Yahao,Hao, Bo,Qin, Kaiwei,Li, Tao,Zhu, Dajian
supporting information, p. 2889 - 2892 (2020/03/18)
In this work, we report the first use of a salen-based hypercrosslinked polymer-supported Pd catalyst to carry out C-H halogenation. This catalyst can effectively catalyze C-H bromination and chlorination even better than its homogeneous counterpart Pd(OAc)2. It also showed excellent reusability without loss of catalytic activity for ten cycles. A broad substrate scope was explored and moderate to excellent yields were obtained.