452956-86-4

Basic information

• Product Name: prop-2-en-1-yl (6S)-9-[ (1R)-1-(benzyloxy)ethyl]-12-[(benzyloxy)methyl]-2,2-dimethyl-4,7,10-trioxo-6-(propan-2-yl)-3-oxa-5,8,11-triazatridecan-13-oate
• Synonyms: prop-2-en-1-yl (6S)-9-[ (1R)-1-(benzyloxy)ethyl]-12-[(benzyloxy)methyl]-2,2-dimethyl-4,7,10-trioxo-6-(propan-2-yl)-3-oxa-5,8,11-triazatridecan-13-oate
• CAS NO: 452956-86-4
• Molecular Weight: 625.762
• Mol File: 452956-86-4.mol

Chemical Properties

• CAS DataBase Reference: prop-2-en-1-yl (6S)-9-[ (1R)-1-(benzyloxy)ethyl]-12-[(benzyloxy)methyl]-2,2-dimethyl-4,7,10-trioxo-6-(propan-2-yl)-3-oxa-5,8,11-triazatridecan-13-oate(CAS DataBase Reference)
• NIST Chemistry Reference: prop-2-en-1-yl (6S)-9-[ (1R)-1-(benzyloxy)ethyl]-12-[(benzyloxy)methyl]-2,2-dimethyl-4,7,10-trioxo-6-(propan-2-yl)-3-oxa-5,8,11-triazatridecan-13-oate(452956-86-4)
• EPA Substance Registry System: prop-2-en-1-yl (6S)-9-[ (1R)-1-(benzyloxy)ethyl]-12-[(benzyloxy)methyl]-2,2-dimethyl-4,7,10-trioxo-6-(propan-2-yl)-3-oxa-5,8,11-triazatridecan-13-oate(452956-86-4)

Safety Data

• Hazardous Substances Data: 452956-86-4(Hazardous Substances Data)

Upstream product

• 13734-41-3 t-Boc-L-valine 
• 1613724-98-3 C₂₉H₃₈N₂O₇ 
• 15260-10-3 N-Boc-O-benzyl-L-threonine 
• 132090-11-0 N-Boc-O-Bn-L-Ser allyl ester 

Downstream Products

• 452956-92-2 (2S)-3-(benzyloxy)-2-{[(2S)-3-(benzyloxy)-2-{[(2S)-2-{[(2R,3R,4S,5R)-3,5-dihydroxy-2,4-dimethyloctadecanoyl]amino}-3-methylbutanoyl]amino}butanoyl]amino}propanoic acid 
• 452956-91-1 prop-2-en-1-yl (2S)-3-(benzyloxy)-2-{[(2S)-3-(benzyloxy)-2-{[(2S)-2-{[(2R,3R,4S,5R)-3,5-dihydroxy-2,4-dimethyloctadecanoyl]amino}-3-methylbutanoyl]amino}butanoyl]amino}propanoate 
• 1613724-91-6 (3S,6S,9S,12R,13R)-6-[1-(benzyloxy)ethyl]-3-[ (benzyloxy)methyl]-13-[(2S,3R)-3-(methoxymethoxy)hexadecan-2-yl]-12-methyl-9-(propan-2-yl)-1-oxa-4,7,10-triazacyclotridecane-2,5,8,11-tetrone 
• 1613724-69-8 (5R,6R,7R,8R,11S,14S,17S)-14-[1-(benzyloxy)ethyl]-17-[(benzyloxy)methyl]-7-hydroxy-6,8-dimethyl-9,12,15-trioxo-11-(propan-2-yl)-5-tridecyl-2,4-dioxa-10,13,16-triazaoctadecan-18-oic acid 
• 452956-88-6 prop-2-en-1-yl (5R,6R,7R,8R,11S,14S,17S)-14-[1-(benzyloxy)ethyl]-17-[(benzyloxy)methyl]-7-hydroxy-2,2,3,3,6,8-hexamethyl-9,12,15-trioxo-11-(propan-2-yl)-5-tridecyl-4-oxa-10,13,16-triaza-3-silaoctadecan-18-oate 
• 1613724-71-2 prop-2-en-1-yl (5R,6R,7R,8R,11S,14S,17S)-14-[1-(benzyloxy)ethyl]-17-[(benzyloxy)methyl]-7-hydroxy-6,8-dimethyl-9,12,15-trioxo-11-(propan-2-yl)-5-tridecyl-2,4-dioxa-10,13,16-triazaoctadecan-18-oate 

Relevant articles and documents

Formal total synthesis of stevastelins B and B3

The formal total synthesis of stevastelins B and B3 (2 and 4, resp.) have been accomplished employing a highly enantiomerically controlled Lewis acid catalyzed non-aldol approach to obtain the syn aldol product and temperature controlled hydroboration oxidation reaction to construct four consecutive stereogenic centers. The other key reactions include Sharpless asymmetric epoxidation, macrolactonization, and macrolactamization towards building the core skeleton 2 and 4. Copyright