456-61-1

Basic information

• Product Name: Benzene, (2,2-dichloro-1,1-difluoroethoxy)-
• CAS NO: 456-61-1
• Molecular Formula: C8H6Cl2F2O
• Molecular Weight: 227.038
• Mol File: 456-61-1.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Benzene, (2,2-dichloro-1,1-difluoroethoxy)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, (2,2-dichloro-1,1-difluoroethoxy)-(456-61-1)
• EPA Substance Registry System: Benzene, (2,2-dichloro-1,1-difluoroethoxy)-(456-61-1)

Safety Data

• Hazardous Substances Data: 456-61-1(Hazardous Substances Data)

Upstream product

• 354-58-5 1,1,1-Trichloro-2,2,2-trifluoroethane 
• 100-67-4 potassium phenolate 
• 76-11-9 1,1-difluorotetrachloroethane 
• 79-35-6 1,1'-dichloro-2,2'-difluoroethene 
• 122-60-1 Phenyl glycidyl ether 
• 306-83-2 1,1,1-trifluoro-2,2-dichloroethane 
• 108-95-2 phenol 
• 354-21-2 1,1,2-trichloro-2,2-difluoroethane 
• 139-02-6 sodium phenoxide 

Downstream Products

• 81787-62-4 o-((trimethylsilyl)ethynyl)phenol 
• 64728-72-9 4-(2,2-dichloro-1,1-difluoroethoxy)benzenesulfonyl chloride 
• 658-47-9 4-<α.α-Difluor-β.β.β-trichlor-aethoxy>-nitrobenzol 
• 713-61-1 α,α-difluoro-β,β,β-trichloroethoxybenzene 
• 457-44-3 (2-chloro-1-fluoro-vinyl)-phenyl ether 

Relevant articles and documents

Unexpected Substitution Reaction of 1,1-Dichloro-2,2,2-trifluoroethane (HCFC-123) with Phenolates

An unexpected substitution reaction of HCFC-123 with phenolates is reported. During the reaction, fluorine atoms in HCFC-123 are removed one by one in the presence of phenolates.

REACTIVITY OF FLUOROOLEFINS IN REACTIONS WITH OXIRANES UNDER BASE CATALYSIS CONDITIONS

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Halocarbon Chemistry. !. (2-Hydroxyaryl)acetylenes from Haloethyl Aryl Ethers. A New O to C Rearrangement.

A new base-induced (BuLi) oxygen-to carbon rearrangement is described which involves the direct conversion of phenyl tetra(or tri)haloethyl ethers and the related intermediate phenoxyalkynes to the corresponding 1-(2-hydroxyphenyl)alkynes in good to excel