460-25-3Relevant articles and documents
Durig et al.
, p. 3805,3806, 3807 (1974)
Copper salt-catalysed reaction of perfluoroalkyl halides with olefins
Igumnov, Sergei M.,Don, Veronika L.,Vyazkov, Vladimir A.,Narinyan, Karen E.
, p. 189 - 190 (2007/10/03)
Perfluoroalkyl halides react with olefins in the presence of copper acetate and hydrazine to give 1,2-addition products.
gem-Difluoroallyllithium: Improved Synthesis Brings Improved Applicability
Seyferth, Dietmar,Simon, Robert M.,Sepelak, Dennis J.,Klein, Helmut A.
, p. 2273 - 2274 (2007/10/02)
The action of n-butyllithium in hexane on CF2BrCH=CH2/CF2=CHCH2Br (5:2 to 20:1 mixture) in 5:1:1 THF/Et2O/pentane at -95 deg C generates gem-difluoroallyllithium which may be trapped, generally in good yield, by an in situ procedure using triorganochlorosilanes (R3SiCF2CH=CH2) and aldehydes and ketones (RR'C(OH)CF2CH=CH2).