460-32-2

Basic information

• Product Name: 3-BROMO-1,1,1-TRIFLUOROPROPANE
• Synonyms: 3-BROMO-1,1,1-TRIFLUOROPROPANE;3,3,3-TRIFLUOROPROPYL BROMIDE;1-BROMO-3,3,3-TRIFLUOROPROPANE;TIMTEC-BB SBB008495;3-BROMO-1 1 1-TRIFLUOROPROPANE 98%;1-Bromo-3,3,3-trifluoropropane 99%;1-Bromo-3,3,3-trifluoropropane99%;3-Bromo-1,1,1-trifluoropropane,98%
• CAS NO: 460-32-2
• Molecular Formula: C₃H₄BrF₃
• Molecular Weight: 176.96
• EINECS: 1592732-453-0
• Mol File: 460-32-2.mol
• Article Data: 4

Chemical Properties

• Melting Point: 62-63℃
• Boiling Point: 62 °C
• Flash Point: >110°C
• Appearance: clear colourless liquid
• Density: 1.662
• Vapor Pressure: 175mmHg at 25°C
• Refractive Index: 1.362-1.364
• CAS DataBase Reference: 3-BROMO-1,1,1-TRIFLUOROPROPANE(CAS DataBase Reference)
• NIST Chemistry Reference: 3-BROMO-1,1,1-TRIFLUOROPROPANE(460-32-2)
• EPA Substance Registry System: 3-BROMO-1,1,1-TRIFLUOROPROPANE(460-32-2)

Safety Data

• Hazard Codes: N-Xi,Xi,N
• Statements: 59-36/37/38
• Safety Statements: 59-37/39-26
• HazardClass: IRRITANT, OZONE DEPLETER
• Hazardous Substances Data: 460-32-2(Hazardous Substances Data)

Usage

Chemical Properties

CLEAR COLOURLESS LIQUID

InChI:InChI=1/C3H4BrF3/c4-2-1-3(5,6)7/h1-2H2

Upstream product

• 460-25-3 1,1-difluoro-1,3-dibromopropane 
• 74-85-1 ethene 
• 75-63-8 Bromotrifluoromethane 
• 677-21-4 1,1,1-trifluoropropylene 
• 590-92-1 3-Bromopropionic acid 
• 2240-88-2 3,3,3-Trifluoropropanol 
• 460-37-7 1,1,1-trifluoro-3-iodopropane 
• 7726-95-6 bromine 
• 421-07-8 1,1,1-trifluoropropane 
• 13749-37-6 3-bromo-1,1,1-trichloropropane 
• 98-08-8 α,α,α-trifluorotoluene 
• 7783-56-4 antimony(III) fluoride 
• 7446-70-0 aluminium trichloride 
• 10035-10-6 hydrogen bromide 

Downstream Products

• 460-37-7 1,1,1-trifluoro-3-iodopropane 
• 421-07-8 1,1,1-trifluoropropane 
• 460-66-2 3-bromo-3-chloro-1,1,1-trifluoro-propane 
• 460-85-5 1-bromo-1,1-dichloro-3,3,3-trifluoro-propane 
• 677-21-4 1,1,1-trifluoropropylene 
• 406-93-9 4,4,4-trifluorobutyric acid 
• 143859-15-8 1,1,1-Trifluoro-3-(phenylseleno)propane 
• 473736-92-4 4-(4-iodo-phenyl)-1-(3,3,3-trifluoro-propyl)-piperidine-4-carbonitrile 
• 473735-54-5 C-[4-(4-Iodo-phenyl)-1-(3,3,3-trifluoro-propyl)-piperidin-4-yl]-methylamine 
• 947701-95-3 3-benzyloxy-N-(3,3,3-trifluoropropyl)-16,17-seco-estra-1,3,5⁽¹⁰⁾-triene-16,17-imide 
• 406-87-1 4,4,4-trifluorobutanal 
• 1446322-00-4 benzyl 2-(3,3,3-trifluoropropyl) hydrazinecarboxylate 
• 1436426-79-7 1-(5-chloro-2-nitrophenyl)-4-(3,3,3-trifluoropropyl)piperazine 
• 1436426-46-8 1-(4,5-dichloro-2-nitrophenyl)-4-(3,3,3-trifluoropropyl)piperazine 

Relevant articles and documents

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Deoxofluorination of Aliphatic Carboxylic Acids: A Route to Trifluoromethyl-Substituted Derivatives

A practical method for the synthesis of functionalized aliphatic trifluoromethyl-substituted derivatives from aliphatic acids is developed. The transformation proceeds with sulfur tetrafluoride in the presence of water as a key additive. Compared to previous methods, the reaction gives products with full retention of stereo- and absolute configuration of chiral centers.

KrF laser induced telomerization of bromides with olefins. Part 1. Self-inhibition and kinetic analysis

The chain reaction of several organic bromides with olefins was induced by a KrF laser. In all cases we found a self-inhibition, leading to a termination of first order in the radical concentration. There is indirect evidence that it is due to molecular bromine, accumulated during the reaction in spite of the presence of olefins. It has not been noticed previously. We show that kinetic analysis is easy also for pulsed excitation, and the example CF3Br + C2H4 is studied in detail. We found rate constants for CF3 + C2H4 → CF3C2H4 (7.2·109 cm3 mol-1 s-1; this is in between two previous values) and for CF3C2H4 + CF3Br → CF3C2H4Br + CF3(1.2·109 cm3 mol-1 s-1) as well as preliminary values for some other reactions.