4609-11-4

Basic information

• Product Name: 1,5-Pentanedione, 1,5-bis(4-methoxyphenyl)-
• CAS NO: 4609-11-4
• Molecular Formula: C19H20O4
• Molecular Weight: 312.365
• Mol File: 4609-11-4.mol

Chemical Properties

• CAS DataBase Reference: 1,5-Pentanedione, 1,5-bis(4-methoxyphenyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: 1,5-Pentanedione, 1,5-bis(4-methoxyphenyl)-(4609-11-4)
• EPA Substance Registry System: 1,5-Pentanedione, 1,5-bis(4-methoxyphenyl)-(4609-11-4)

Safety Data

• Hazardous Substances Data: 4609-11-4(Hazardous Substances Data)

Usage

Uses

a. Dye intermediate
b. Production of organic pigments

Physical state

Yellow crystalline solid

Melting point

87-88°C

Solubility

Soluble in organic solvents such as acetone, ethanol, and benzene

Applications

a. Production of dyes
b. Inks
c. Coatings

Stability

Relatively stable under normal conditions

Safety precautions

a. Harmful if ingested
b. Avoid contact with skin and eyes
c. Handle with care and follow proper safety measures

Upstream product

• 13139-86-1 4-methoxyphenyl magnesium bromide 
• 5289-37-2 [bis(4-methoxyphenyl)methylene]cyclobutane 
• 47172-89-4 diphenyl glutarate 
• 157367-54-9 2,6-Bis(4-methoxyphenyl)-1,6-heptadiene 
• 170647-10-6 2,4-Bis-(4-methoxy-benzoyl)-1,5-bis-(4-methoxy-phenyl)-pentane-1,5-dione 
• 67-56-1 methanol 
• 179938-57-9 1,2-bis(4-methoxyphenyl)cyclopent-1-ene 
• 2873-74-7 gloutaric dichloride 
• 100-66-3 methoxybenzene 
• 103-73-1 Phenetole 
• 20837-35-8 1,5-bis-(4-hydroxy-phenyl)-pentane-1,5-dione 
• 77-78-1 dimethyl sulfate 

Downstream Products

• 857685-43-9 1,5-di(4-methoxyphenyl)-5-hexen-1-one 
• 179938-57-9 1,2-bis(4-methoxyphenyl)cyclopent-1-ene 
• 104802-63-3 2,4-Bis-azepan-1-yl-1,5-bis-(4-methoxy-phenyl)-pentane-1,5-dione 
• 393827-60-6 C₃₃H₃₂O₂ 
• 157367-54-9 2,6-Bis(4-methoxyphenyl)-1,6-heptadiene 
• 104802-69-9 2,4-Dibromo-1,5-bis-(4-methoxy-phenyl)-pentane-1,5-dione 
• 101684-60-0 2-{[Bis-(2-chloro-ethyl)-amino]-methyl}-1,5-bis-(4-methoxy-phenyl)-4-methylene-pentane-1,5-dione; hydrochloride 
• 100210-60-4 4,4'-(cyclopenta-1,3-diene-1,2-diyl)bis(methoxybenzene) 

Relevant articles and documents

Ring-opening of tertiary cyclopropanols derived from β-diketones

The ring-opening reaction of 1,2-disubstituted cyclopropanols, prepared from β-diketones, mediated by Cu(NO3)2, p-TsOH, and NaOH is reported. The Cu(II)-mediated ring-opening of cyclopropanols gave α-methylene-γ-diketones in good yie

Electrooxidative formation of 1,2-diaroylcyclopropanes from 1,3-diaroylpropanes in the presence of KI

Various 1,2-diaroylcyclopropanes were obtained in good yields by the indirect electrochemical oxidation of 1,3-diaroylpropanes in the presence of catalytic amounts of KI under very mild conditions.

Synthesis, Fe(II)-induced degradation, and antimalarial activities of 1,5-diaryl-6,7-dioxabicyclo[3.2.2]nonanes: Direct evidence for nucleophilic O-1,2-aryl shifts

1,5-Diaryl-6,7-dioxabicyclo[3.2.2]nonanes 1a-d (1a: Ar=p-FC6H4, 1b: Ar=Ph, 1c: Ar=p-MeC6H4, 1d: Ar=p-MeOC6H4) were prepared by a modified method of photo-electron transfer oxygenation, and the reactions of 1 with FeBr2 were investigated under various conditions. The Fe(II)-induced degradation of 1 afforded various rearrangement products and fragmentation products through competitive single electron transfer (SET) and Lewis acid pathways. Direct evidence for the O-1,2-aryl shift was obtained by the isolation of rearrangement products, 1-aryloxy-5-aryl-8-oxabicyclo[3.2.1]octanes 8. The degradation mechanism was proposed and the in vitro antimalarial activities were also evaluated.

Synthesis and fluorescence emission behavior of anti-[2.3](3,10)phenanthrenophane: Overlap between phenanthrene rings required for excimer formation

Novel anti-[2.3](3,10)phenanthrenophane 3, prepared by the intramolecular [2 + 2] photocycloaddition of 1,3-bis(3-vinyl-10-phenanthryl)propane, exhibited monomer fluorescence. This is in a remarkable contrast with the excimer fluorescence emission from an

Photoinduced Electron Transfer (PET) cyclization and photooxygenation of 2,6-diaryl-1,6-heptadienes and 2,7-diaryl-1,7-octadienes

The 2,6-diaryl-substituted 1,6-heptadienes 3a-c and the 2,7-diaryl-substituted 1,7-octadienes 4a-b were cleanly converted into the corresponding anellated cyclobutanes 5 and 6, resp., when irradiated under photoelectron-transfer conditions (9,10-dicyanoanthracene in acetonitrile). Only for 4c did the rearranged compound 7c become the dominant photoproduct. Oxygen trapping experiments with formation of endoperoxides 8, 9 were successful in the case of the electron-rich substrates 3b, c and 4c. VCH Verlagsgesellschaft mbH, 1996.

Highly Selective Aldol Reaction of Dibenzoylmethanes with Formaldehyde Catalyzed by Cobalt Schiff Base Complex under Neutral Conditions

Coordinatively saturated hydroxocobalt(III) Schiff base complexes catalyze highly selective aldol reaction of dibenzoylmethanes with formaldehyde in methanol to give 1,3-dibenzoylpropanes, resulting from retro-Claisen reaction of 1,1,3,3-tetrabenzoylpropanes, which are obtained quantitatively in dichlorometane.Coordinatively saturated cobalt(III) Schiff base complexes ligating a substrate anion as a monodentate ligand is found to be the reactive species.