46835-41-0Relevant articles and documents
Dual Nickel- And Photoredox-Catalyzed Reductive Cross-Coupling of Aryl Halides with Dichloromethane via a Radical Process
Xu, Tao,Xu, Wenhao,Zheng, Purui
supporting information, (2020/11/13)
The first catalytic strategy to harness a new chloromethane radical from dichloromethane under dual Ni/photoredox catalytic conditions has been developed. Compared with traditional two-electron reductive process associated with metallic reductants, this method via a single-electron approach can proceed under exceptionally mild conditions (visible light, ambient temperature, no strong base) and exhibits complementary reactivity patterns. It affords a broad scope of many functional groups, including alkenyl, which suffers cyclopropanation in previous routes. The diarylmethane-d2 compounds can be readily available with this transformation.
Divinyl aromatic compounds and Di(methacrylates) prepared by acid-catalyzed transformations of bis[4-(1-hydroxyethyl)phenyl]alkanes
Zaitsev,Shvabskaya
experimental part, p. 1783 - 1794 (2012/02/15)
The mechanism of formation of divinyl aromatic monomers including p,p′-divinyldiphenylmethane and 1,2-p,p′-divinyldiphenylethane and of their dimerization via terminal vinyl groups was studied. The factors affecting the structure, composition, and propert
