4722-94-5Relevant articles and documents
Linking of antitumor trans NHC-Pt(II) complexes to G-quadruplex DNA ligand for telomeric targeting
Betzer, Jean-Fran?ois,Nuter, Frédérick,Chtchigrovsky, Mélanie,Hamon, Florian,Kellermann, Guillaume,Ali, Samar,Calméjane, Marie-Ange,Roque, Sylvain,Poupon, Jo?l,Cresteil, Thierry,Teulade-Fichou, Marie-Paule,Marinetti, Angela,Bombard, Sophie
, p. 1456 - 1470 (2016)
G-quadruplex structures (G4) are promising anticancerous targets. A great number of small molecules targeting these structures have already been identified through biophysical methods. In cellulo, some of them are able to target either telomeric DNA and/o
Heavy metal complexes of 4-chlorodipicolinic acid - structural, spectral and thermal correlations
Vargová,Almá?i,Gyepes,Vetráková
, p. 3013 - 3029 (2019)
The ligand, 4-chloro-2,6-dipicolinic acid (H2PDA-Cl), and its two heavy metal complexes, [Ag(HDPA-Cl)(H2DPA-Cl)·2H2O] (1) and {[Cd(μ2-H2O)(H2O)(PDA-Cl)]}n (2), were prepared and then characterized by single-crystal X-ray diffraction. In addition, spectral and thermal correlations with structural results complete their solid-state description and facilitate complex 3 ([Pb(DPA-Cl)]) composition determinations. Complex 1 crystallizes in a monoclinic space group C2/c and each DPA-Cl ligand is tridentate to Ag(I) through the pyridine N and two monodentate carboxyl O atoms. The carboxy group with carbonyl C1 is semideprotonated and forms a symmetric hydrogen bond with a carboxy group of a neighboring complex. Complex 2 crystallizes in a triclinic lattice with space group P (Formula presented.) The Cd(II) ions are seven-coordinate and the coordination polyhedra can be described as a distorted pentagonal bipyramid. IR data are consistent with monodentate coordination of the carboxylate to Ag(I), Cd(II), and Pb(II) and observed wavenumber shifts confirm PDA-Cl ligand coordination to Pb(II) in 3. Thermal stability of anhydrous complexes indicates the metal–ligand interactions. The thermal stability of prepared compounds is reflected by the strength of interaction between metal–ligand and hydrogen bonds.
A formal anti-Markovnikov hydroalkoxylation of allylic alcohols with a ruthenium catalyst
Nakamura, Yushi,Ohta, Tetsuo,Oe, Yohei
supporting information, p. 288 - 291 (2018/02/14)
Hydroalkoxylation of C-C double bonds was achieved through the use of a ruthenium catalyst. The reaction of allylic alcohols with nucleophilic alcohols was carried out in the presence of a ruthenium catalyst prepared by RuClH(CO)(PPh3)3 and 2,6-bis(n-butyliminomethyl)-4-(piperidin-1-yl)pyridine under mild reaction conditions to afford the corresponding γ-alkoxypropanols in good yield.
Modified Colorants and Inkjet Ink Compositions Comprising Modified Colorants
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Paragraph 0146-0147, (2016/04/09)
The present invention relates to a modified colorant comprising a colorant having attached at least one organic group. Various embodiments of the organic group are disclosed. For each of these embodiments, preferably the organic group has a defined calciu