4743-97-9

Upstream product

• 53063-63-1 5-hydroxy-3-oxo-5-phenyl-valeric acid methyl ester 
• 1127435-37-3 tert-butyl (4E)-3-carbonyl-5-phenyl-4-pentenoate 
• 1743-36-8 1-phenylbut-3-yn-1-ol 
• 682770-63-4 5-butyryloxy-3-oxo-5-phenyl-pentanoic acid ethyl ester 
• 682770-55-4 5-butyryloxy-3-oxo-5-phenyl-pentanoic acid methyl ester 
• 100-52-7 benzaldehyde 
• 682770-94-1 (5S) ethyl δ-butyryloxy-δ-phenyl-β-oxo-pentanoate 
• 682770-83-8 (5S) methyl δ-butyryloxy-δ-phenyl-β-oxo-pentanoate 
• 122-57-6 1-Phenylbut-1-en-3-one 
• 77-92-9 citric acid 
• 54814-82-3 5-hydroxy-5-phenylpent-2-ynoic acid 
• 63164-89-6 3-ethoxy-5-phenyl-penta-2,4-dienoic acid 

Downstream Products

• 1392149-68-6 (3R,3E)-tert-butyl 3-hydroxy-2-oxo-3-(2-oxo-4-phenylbut-3-enyl)-2,3-dihydro-1H-indoline-1-carboxylate 
• 1533453-30-3 (E)-5-benzyl-5-methyl-1-phenylhepta-1,6-dien-3-one 
• 1533453-15-4 (E)-5-cyclohexyl-1-phenylhepta-1,6-dien-3-one 

Relevant academic research and scientific papers

α-Carboxylation Reactions of Ketones with a Bromomagnesium Thioureide-Carbon Dioxide Complex

The magnesium complex (1) has been found to undergo fixation of carbon dioxide and the resulting carboxylato-complex (2) transfers the carboxylato group to several ketones with good yields.

Stereoselective Synthesis of Diverse Lactones through a Cascade Reaction of Rhodium Carbenoids with Ketoacids

A convergent cascade approach for the stereoselective synthesis of diverse lactones is described. The Rh2(TFA)4-catalyzed cascade reaction proceeds via a carboxylic acid O-H insertion/aldol cyclization with high chemo-, regio-, and d

A Chemoenzymatic Approach to Optically Active 5-Hydroxy-3-oxocarboxylates

Enzymatic hydrolysis was applied to the preparation of certain chiral 5-hydroxy-3-oxo-carboxylates that are potential precursors for natural product synthesis via the formation of lactone derivatives and tetrahydropyran rings.

The Function of Magnesium(II) N,N'-Dicyclohexylamidinide Complexes as a Carbon Dioxide Carrier

It is found that magnesium(II) N,N'-dicyclohexylamidinide complexes are useful reagents for the fixation of carbon dioxide and the transfer of the captured carbon dioxide moiety to active methylene compounds.

2-Morpholinoimidazolinomagnesium(II) Complex as a Novel Carbon Dioxide Carrier

The magnesium complex (1) has been found to undergo fixation of carbon dioxide and the resulting 1-carboxylato-complex (2) transfers the carboxylato group to active methylene compounds (3) including acetophenone, benzylideneacetone, β-ionone, and S-benzyl thioacetate, under mild conditions.