α-Carboxylation Reactions of Ketones with a Bromomagnesium Thioureide-Carbon Dioxide Complex

DOI: 10.1039/c39830001487

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1487 - 1488 (1983)

Update date:2022-08-29

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Authors:

Matsumura, Noboru

Asai, Nobuyuki

Yoneda, Shigeo

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Article abstract of DOI:10.1039/c39830001487

The magnesium complex (1) has been found to undergo fixation of carbon dioxide and the resulting carboxylato-complex (2) transfers the carboxylato group to several ketones with good yields.

Full text of DOI:10.1039/c39830001487

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