474958-86-6

Upstream product

• 202589-95-5 (1S,2S)-1-phenyl-but-3-ene-1,2-diol 
• 77-76-9 2,2-dimethoxy-propane 
• 474958-70-8 (1S,2S)-2-(2-methoxy-ethoxymethoxy)-1-phenyl-but-3-en-1-ol 
• 100-52-7 benzaldehyde 
• 675834-57-8 (1S,2S)-1-phenyl-1-(tert-butyldimethylsilyloxy)but-3-en-2-ol 

Downstream Products

• 153481-85-7 (4R,5S)-2,2-dimethyl-5-phenyl-[1,3]-dioxolane-4-carbaldehyde 
• 153609-00-8 (4S,5S)-2,2-dimethyl-4-(hydroxymethyl)-5-phenyl-1,3-dioxolane 
• 474958-88-8 [(1R)-1-((4S,5S)-2,2-dimethyl-5-phenyl-[1,3]-dioxolan-4-yl)-but-3-enyl]-3-phenyl prop-2-enoate 
• 474958-89-9 (6R)-6-[(4S,5S)-2,2-dimethyl-5-phenyl-1,3-dioxolan-4-yl]-5,6-dihydro-2H-pyran-2-one 
• 146236-73-9 (6R)-6-[(1R,2S)-1,2-dihydroxy-2-phenylethyl]-5,6-dihydro-2H-pyran-2-one 
• 136685-37-5 (1R,5R,7S,8S)-8-hydroxy-7-phenyl-2,6-dioxa-bicyclo-[3.3.1]-nonan-3-one 

Relevant academic research and scientific papers

Stereoselective synthesis of γ-substituted (Z)-allylic boranes via kinetically controlled hydroboration of allenes with 10-TMS-9-borabicyclo[3.3.2] decane

(Chemical Equation Presented) Kinetically controlled hydroboration of allenes 8 and 14a-d with the readily accessible Soderquist borane 7, which is generated in situ from borohydride 6, constitutes a convenient and preparatively useful method for synthesi

Revision of stereochemical assignments of (2,2-dimethyl-5-phenyl-[1,3] dioxolan-4-yl)-methanol

Opposite signs of specific rotation are reported in the literature for (4S,5S)-(2,2-dimethyl-5-phenyl-[1,3]dioxolan-4-yl)-methanol. The correct assignment was made by unambiguous synthesis of the title compound via the reaction of (S)-O-TBS-mandelic aldeh

Stereoselective syntheses of (+)-goniodiol, (-)-8-epigoniodiol, and (+)-9-deoxygoniopypyrone via alkoxyallylboration and ring-closing metathesis

A convenient synthesis of (+)-goniodiol, (-)-8-epigoniodiol, and (+)-9-deoxygoniopypyrone has been developed via asymmetric alkoxyallylboration and ring-closing metathesis pathways.