482656-47-3Relevant articles and documents
Total synthesis of aeruginosin 98B
Trost, Barry M.,Kaneko, Toshiyuki,Andersen, Neil G.,Tappertzhofen, Christoph,Fahr, Bruce
supporting information, p. 18944 - 18947 (2013/01/15)
The first total synthesis of aeruginosin 98B was accomplished. The key step is a highly diastereoselective Pd-catalyzed intramolecular asymmetric allylic alkylation reaction of a diastereomeric mixture of allylic carbonates that is enabled by the use of racemic phosphine ligand L1.
Efficient synthesis of antihyperglycemic (S)-alpha-aryloxy-beta-phenylpropionic acid using a bifunctional asymmetric catalyst.
Takamura, Makoto,Yanagisawa, Hiroaki,Kanai, Motomu,Shibasaki, Masakatsu
, p. 1118 - 1121 (2007/10/03)
Antihyperglycemic (S)-alpha-aryloxy-beta-phenylpropionic acid was prepared using catalytic asymmetric cyanosilylation as a key reaction to construct alpha-oxycarboxylic acid moiety.