4887-98-3

Usage

Uses

Used in Organic Synthesis:
1-chloroanthracen-9(10H)-one is used as a key intermediate in the synthesis of other organic compounds, contributing to the development of new chemical entities and materials.
Used in Research Applications:
1-chloroanthracen-9(10H)-one is utilized in various research applications, where its chemical properties and reactivity are explored to advance scientific understanding and innovation in organic chemistry.
Used in Industrial Processes:
1-chloroanthracen-9(10H)-one is employed in different industrial processes, where its unique structure and properties are leveraged to improve or enable specific chemical reactions and product development.

InChI:InChI=1/C14H9ClO/c15-12-7-3-5-10-8-9-4-1-2-6-11(9)14(16)13(10)12/h1-7H,8H2

Upstream product

• 82-44-0 1-chloroanthracene-9,10-dione 
• 7664-93-9 sulfuric acid 
• 15534-53-9 1-chloroanthrahydroquinone 
• 7647-01-0 hydrogenchloride 
• 71-43-2 benzene 
• 10034-85-2 hydrogen iodide 
• 64-19-7 acetic acid 
• 103037-16-7 4,4'-dichloro-9H,9'H-[9,9']bianthryl-10,10'-dione 

Downstream Products

• 5356-02-5 1-Chlor-anthrachinon-(9.10.)-monoanil ⁽¹⁰⁾ 
• 82-44-0 1-chloroanthracene-9,10-dione 
• 43099-09-8 6-anilino-benz[de]anthracen-7-one 
• 60435-28-1 6-p-toluidino-benz[de]anthracen-7-one 
• 60435-29-2 6-(4-chloro-anilino)-benz[de]anthracen-7-one 
• 5385-42-2 1-Chlor-anthrachinon-(9,10)-triphenylphosphazin 
• 860729-73-3 9-benzyl-1-chloro-9,10-dihydro-[9]anthrol 

Relevant academic research and scientific papers

Reduction of 1-substituted anthraquinones to 1- and 4-substituted anthrones

The regioselectivity of reduction of 1-substituted anthraquinones to 1 - or 4-substituted anthrones is determined by both the nature of the substituent and the type of the reducing system used.

Pyrolysis of Aryl Azides. XI. Enhanced Neighbouring Group Effects of Carbonyl in a Locked Conformation

Rates of pyrolysis in nitrobenzene solution have been measured for 1-azido-9H-fluoren-9-one, 1-azido-9H-xanthen-9-one, 1-azidoacridin-9(10H)-one and 1-azidoanthracene-9,10-dione; relative to azidobenzene at 120 deg these were respectively 5.68, 1750, 5090 and 18400.The lack of neighbouring group participation for the first azide is related to the large distance between carbonyl oxygen and the inner azido nitrogen atom, and the data argue against a published proposal that the transition state is stabilized by electrostatic attraction.In the remaining azides, the 'locked conformation' leads to much larger neighbouring group assistance than is observed for freely rotating ortho groups such as benzoyl rel 79).Only the last azide yields an isoxazole on pyrolysis, the second and third ones providing the first reported examples of neighbouring-group-assisted pyrolysis in which no cyclic product is obtained.These results are interpreted in terms of an electrocyclic mechanism in which the transition state is early and N---O bond formation is less advanced than other changes in bonds.Much of the rate enhancement is attributed to an electron distribution which favours nitrogen loss. 1-Aminoanthracen-9(10H)-one, 1-amino-9H-fluoren-9-one and 1-amino-9H-xanthen-9-one do not yield the corresponding isoxazoles when oxidative cyclization is attempted.