494865-05-3

Basic information

• Product Name: 2-Propenoic acid, 3,3-bis(4-bromophenyl)-, ethyl ester
• CAS NO: 494865-05-3
• Molecular Formula: C17H14Br2O2
• Molecular Weight: 410.105
• Mol File: 494865-05-3.mol
• Article Data: 14

Chemical Properties

• CAS DataBase Reference: 2-Propenoic acid, 3,3-bis(4-bromophenyl)-, ethyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: 2-Propenoic acid, 3,3-bis(4-bromophenyl)-, ethyl ester(494865-05-3)
• EPA Substance Registry System: 2-Propenoic acid, 3,3-bis(4-bromophenyl)-, ethyl ester(494865-05-3)

Safety Data

• Hazardous Substances Data: 494865-05-3(Hazardous Substances Data)

Upstream product

• 10605-43-3 1,1-bis(p-bromophenyl)ethylene 
• 109-94-4 formic acid ethyl ester 
• 589-87-7 1,4-bromoiodobenzene 
• 140-88-5 ethyl acrylate 
• 867-13-0 diethoxyphosphoryl-acetic acid ethyl ester 
• 3988-03-2 bis(4-bromophenyl)methanone 

Downstream Products

• 1437756-77-8 7-bromo-4-(4-bromophenyl)-2H-chromen-2-one 
• 673479-09-9 {4-[3,3-Bis-(4-bromo-phenyl)-allylsulfanyl]-2-methyl-phenoxy}-acetic acid 
• 673479-08-8 methyl {4-[3,3-bis-(4-bromo-phenyl)-allylsulfanyl]-2-methyl-phenoxy}-acetate 
• 685139-10-0 {4-[3,3-bis-(4-bromo-phenyl)-allylsulfanyl]-2-chloro-phenoxy}-acetic acid 
• 685138-99-2 methyl {4-[3,3-bis-(4-bromo-phenyl)-allylsulfanyl]-2-chloro-phenoxy}-acetate 
• 494865-21-3 ethyl {4-[3,3-bis-(4-bromo-phenyl)-allyloxy]-3-chloro-phenyl}-acetate 
• 494865-09-7 ethyl {3-[3,3-bis-(4-bromo-phenyl)-allyloxy]-phenyl}-acetate 
• 494865-16-6 methyl {4-[3,3-bis-(4-bromo-phenyl)-allyloxy]-phenyl}-acetate 
• 494865-03-1 3-{3-[3,3-bis-(4-bromo-phenyl)-allyloxy]-phenyl}-propionic acid ethyl ester 
• 494865-12-2 ethyl 3-{4-[3,3-bis-(4-bromo-phenyl)-allyloxy]-phenyl}-propionate 
• 303110-96-5 3,3-bis-(4-bromophenyl)-prop-2-en-1-ol 

Relevant articles and documents

Photoinduced Oxidative Alkoxycarbonylation of Alkenes with Alkyl Formates

A photoinduced oxidative alkoxycarbonylation of alkenes initiated by intermolecular addition of alkoxycarbonyl radicals has been demonstrated. Employing alkyl formates as alkoxycarbonyl radical sources, a range of α,β-unsaturated esters were obtained with good regioselectivity and E selectivity under ambient conditions.

Synthesis of coumarins via PIDA/I2-mediated oxidative cyclization of substituted phenylacrylic acids

A variety of functionalized coumarins were synthesized from substituted phenylacrylic acids via PIDA/I2-mediated and irradiation-promoted oxidative carbon-oxygen bond formation. Our studies show that the oxygen in the pendant carboxylic acid group cyclizes favorably to the aryl ring that is cis to it. The main advantages of this method include good functional group tolerance and the transition-metal-free characteristic. The Royal Society of Chemistry 2013.

Palladium-catalyzed intramolecular amidation of C(sp2)-H bonds: Synthesis of 4-aryl-2-quinolinones

Figure presented A catalytic synthetic approach for the synthesis of 2-quinolinone compounds through a Pd-catalyzed C(sp2)-H functionalization/intramolecular amidation sequence is described. The cyclization process efficiently proceeds in the p