497065-79-9

Upstream product

• 136824-22-1 methyl (2R,3R)-α-azido-β-(dimethylphenylsilyl)-(E)-hex-4-enoate 

Downstream Products

• 497065-57-3 (2S,5R,6S)-1-benzyloxycarbonyl-5-methyl-6-(4'-acetoxybutyl)-1,2,5,6-tetrahydropyridine-2-carboxylic acid methyl ester 
• 1027942-14-8 (2S,5R,6S)-6-(4-Acetoxy-butyl)-5-methyl-piperidine-1,2-dicarboxylic acid 1-benzyl ester 2-methyl ester 
• 1026246-64-9 (2S,5R,6R)-6-[4-(3-Methoxy-prop-1-ynyl)-phenyl]-5-methyl-1-(2,2,2-trifluoro-acetyl)-piperidine-2-carboxylic acid methyl ester 
• 1026752-53-3 (2S,5R,6R)-6-(4-Furan-2-yl-phenyl)-5-methyl-1-(2,2,2-trifluoro-acetyl)-piperidine-2-carboxylic acid methyl ester 
• 916915-00-9 (2S,5R,6R)-6-(4-Bromo-phenyl)-5-methyl-1-(2,2,2-trifluoro-acetyl)-piperidine-2-carboxylic acid methyl ester 
• 916915-01-0 (2S,5R,6R)-6-(3-Bromo-phenyl)-5-methyl-1-(2,2,2-trifluoro-acetyl)-piperidine-2-carboxylic acid methyl ester 
• 916914-58-4 (2S,5R,6R)-5-methyl-6-(3-morpholinophenyl)piperidine-2-carboxylic acid 
• 1027921-30-7 (2S,5R,6R)-5-Methyl-6-(3-morpholin-4-yl-phenyl)-piperidine-2-carboxylic acid methyl ester 
• 916914-97-1 (2S,5R,6R)-1-(2,2,2-trifluoroacetyl)-5-methyl-6-(4-bromophenyl)-1,2,5,6-tetrahydropyridine-2-carboxylic acid methyl ester 
• 916914-98-2 methyl (2S,5R,6R)-6-(3-bromophenyl)-1-(2,2,2-trifluoroacetyl)-1,2,5,6-tetrahydro-5-methylpyridine-2-carboxylate 
• 916914-99-3 methyl (2S,5R,6R)-6-(2-bromophenyl)-1-(2,2,2-trifluoroacetyl)-1,2,5,6-tetrahydro-5-methylpyridine-2-carboxylate 
• 916914-53-9 (2S,5R,6R)-6-(4-(3-methoxyprop-1-ynyl)phenyl)-5-methylpiperidine-2-carboxylic acid 
• 916914-63-1 (2S,5R,6R)-6-(4-acetylaminophenyl)-5-methylpiperidine-2-carboxylic acid 
• 916914-47-1 (2S,5R,6R)-6-(4-(furan-2-yl)phenyl)-5-methylpiperidine-2-carboxylic acid 

Relevant academic research and scientific papers

Diastereoselectivity in the Osmium Tetraoxide Promoted Dihydroxylation of Chiral (E)-Crotylsilanes: Asymmetric Synthesis of Silyl-Functionalized γ-Lactones

The catalytic osmylation of enantiomerically enriched (E)-crotylsilanes (2S,3R)-1 and (2R,3R)-2 containing a homoallylic, nitrogen-bearing stereocenter proceeds with good to high levels of diastereoselection generating silyl-functionalized trans-4,5-subst