4985-70-0

Basic information

• Product Name: 1-CHLOROANTHRACENE
• Synonyms: 1-CHLOROANTHRACENE;1-Chloroanthracene 95%
• CAS NO: 4985-70-0
• Molecular Formula: C₁₄H₉Cl
• Molecular Weight: 212.67
• EINECS: 225-641-5
• Product Categories: Aryl;C13 to C37+;Halogenated Hydrocarbons;Building Blocks;C13 to C37+;Chemical Synthesis;Halogenated Hydrocarbons;Organic Building Blocks
• Mol File: 4985-70-0.mol
• Article Data: 6

Chemical Properties

• Melting Point: 77-80 °C(lit.)
• Boiling Point: 275.35°C (rough estimate)
• Flash Point: 179.2°C
• Appearance: /
• Density: 1.171 g/mL at 25 °C(lit.)
• Vapor Pressure: 2.42E-05mmHg at 25°C
• Refractive Index: 1.6959
• CAS DataBase Reference: 1-CHLOROANTHRACENE(CAS DataBase Reference)
• NIST Chemistry Reference: 1-CHLOROANTHRACENE(4985-70-0)
• EPA Substance Registry System: 1-CHLOROANTHRACENE(4985-70-0)

Safety Data

• WGK Germany: 3
• Hazardous Substances Data: 4985-70-0(Hazardous Substances Data)

Usage

Description

1-Chloroanthracene forms photodimer trans-bi(1-chloro-9,10-dihydro-9,10-anthracenediyl) via the solid-state [4+4]-photodimerization.1-Chloroanthracene was used to investigate the effect of polycyclic aromatic hydrocarbons on gap junctional intercellular communication and activation of intracellular receptor kinase in F344 rat liver epithelial cells.

Uses

1-Chloroanthracene was used to investigate the effect of polycyclic aromatic hydrocarbons on gap junctional intercellular communication and activation of intracellular receptor kinase in F344 rat liver epithelial cells.

Synthesis Reference(s)

The Journal of Organic Chemistry, 51, p. 1914, 1986 DOI: 10.1021/jo00360a054

General Description

1-Chloroanthracene forms photodimer trans-bi(1-chloro-9,10-dihydro-9,10-anthracenediyl) via the solid-state [4+4]-photodimerization.

InChI:InChI=1/C14H9Cl/c15-14-7-3-6-12-8-10-4-1-2-5-11(10)9-13(12)14/h1-9H

Upstream product

• 6406-96-8 1,5-dichloroanthracene 
• 56-23-5 tetrachloromethane 
• 82-44-0 1-chloroanthracene-9,10-dione 
• 7664-41-7 ammonia 
• 77287-34-4 formamide 
• 79917-76-3 N-(4-Chloro-anthracen-9-yl)-formamide 
• 4888-02-2 4-chloroanthrone 

Downstream Products

• 33188-82-8 1-chlorotriptycene 
• 1171-95-5 1-anthryldiphenyl-phosphine 
• 195-06-2 Dibenzophenanthren 
• 120-12-7 anthracene 
• 64819-61-0 1-isopropylanthracene 
• 66291-35-8 1-ethylanthracene 
• 3752-42-9 anthracene-1-carbonitrile 
• 1079-71-6 1,2,3,4,5,6,7,8-octahydroanthracene 
• 613-31-0 9,10-dihydroanthracene 
• 2141-42-6 1,2,3,4-tetrahydroanthracene 
• 10035-10-6 hydrogen bromide 
• 610-50-4 1-hydroxyanthracene 
• 22980-71-8 8,10-dichloroanthracene 

Relevant articles and documents

Efficient indium-mediated dehalogenation of aromatics in ionic liquid media

An efficient indium-mediated dehalogenation reaction of haloaromatics and haloheteroaromatics in ionic liquids has been studied. This method is simple and effective in the presence of [bmim]Br. Furthermore, this methodology is environmentally friendly compared with conventional ones.

Benzannulated Isobenzofurans

A number of arynes, generated by treatment of haloarenes with sodium or potassium amide in tetrahydrofuran, were trapped with furan.The resulting dihydro epoxy arenes were converted into the following annulated isobenzofuran derivatives by using reverse Diels-Alder methodology: naphthofuran, phenanthrofuran, pyrenofuran, pyrenofuran, anthrafuran, phenanthrofuran and phenathrofuran.Bimolecular rate constants for the addition of maleic anhydride to these furans were measured, and were correlated with the Herndon structure count.Addition of arynes to selected members of this furan series yielded adducts which were deoxygenated to afford polycyclic aromatic hydrocarbons.

Anomalous Course of Leuckart Reduction of Anthraquinones by Formamide

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