500530-77-8

Basic information

• Product Name: Benzene, 1,4-bis[(1E)-2-[4-[(1,1-dimethylethyl)thio]phenyl]ethenyl]-
• CAS NO: 500530-77-8
• Molecular Formula: C30H34S2
• Molecular Weight: 458.732
• Mol File: 500530-77-8.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: Benzene, 1,4-bis[(1E)-2-[4-[(1,1-dimethylethyl)thio]phenyl]ethenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1,4-bis[(1E)-2-[4-[(1,1-dimethylethyl)thio]phenyl]ethenyl]-(500530-77-8)
• EPA Substance Registry System: Benzene, 1,4-bis[(1E)-2-[4-[(1,1-dimethylethyl)thio]phenyl]ethenyl]-(500530-77-8)

Safety Data

• Hazardous Substances Data: 500530-77-8(Hazardous Substances Data)

Upstream product

• 88357-16-8 4-(1,1-dimethylethylthio)benzaldehyde 
• 4546-04-7 tetraethyl 1,4-xylylenediphosphonate 
• 25752-90-3 tert-butyl 4-bromophenyl sulfide 
• 106-53-6 para-bromobenzenethiol 

Relevant articles and documents

New cruciform structures: Toward coordination induced single molecule switches

(Chemical Equation Presented) New cruciform structures 1-4 were synthesized to investigate a new single molecule switching mechanism arising from the interplay between the molecule and the electrode surface. These molecular cruxes consist of two rod-type

Novel synthesis of protected thiol end-capped stilbenes and oligo(phenylenevinylene)s (OPVs)

The first general procedures for preparation of thiol end-capped stilbenes and oligo(phenylenevinylene)s (OPVs) with tert-butyl- and acetyl-protected thiol termini have been developed. These reactions proceed via Br/Li exchange, McMurry, and Wittig-type reactions. The thiol functionality is protected against strong basic and acidic reaction conditions as a t-Bu sulfide. As a key point in the method, reprotection of the thiol group is accomplished by means of acetyl chloride and boron tribromide. The novel strategy forms the basis for stepwise introduction of 4-mercaptostyryl units in OPVs. The new mono-, di-, and trimercapto OPVs have potential applications as one, two, and three terminal molecular devices in gold nanoparticle clusters, self-assembled monolayers, and optoelectronic devices.