501418-47-9Relevant academic research and scientific papers
The addition polymerization of a P=C bond: A route to new phosphine polymers
Tsang, Chi-Wing,Yam, Mandy,Gates, Derek P.
, p. 1480 - 1481 (2003)
Addition polymerization, the most general method of preparation for organic polymers, has successfully been extended to P=C bonds. The polymerization of a phosphaalkene has been initiated by thermolysis or with alkyllithium reagents. The unprecedented pol
Analysis of the products of the anionic oligomerisation of a phosphaalkene using MALDI-TOF mass spectrometry
Gillon, Bronwyn H.,Gates, Derek P.
, p. 1868 - 1869 (2004)
The first use of MALDI-TOF MS in the study of the products of RLi (R = Me, Bu) initiated oligomerisation of P=C bonds is reported. These studies may be considered as models for analogous polymerisation reactions. The detected linear products with R-P and
Molecular studies of the initiation and termination steps of the anionic polymerization of P=C bonds
Gillon, Bronwyn H.,Noonan, Kevin J.T.,Feldscher, Bastian,Wissenz, Jennifer M.,Kam, Zhi Ming,Hsieh, Tom,Kingsley, Justin J.,Bates, Joshua I.,Gates, Derek P.
, p. 1045 - 1052 (2008/09/16)
The initiation and termination steps of the anionic polymerization of P=C bonds have been modeled. The initiation step was investigated through the stoichiometric reaction of MesP=CPh2 (1) with RLi (R = Me or n-Bu). In each case, the addition w
A NUCLEOPHILIC REACTION OF A PHOSPHAALKENE: THE METHYLATION OF MESITYLDIPENYLMETHYLENEPHOSPHINE
Knaap, Th. A. van der,Bickelhaupt, F.
, p. 2037 - 2040 (2007/10/02)
The reaction of the title compound (1) with methyl iodide gives the ylide 3 and the phosphonium salt 4.The intermediate formation of the phosphoniaalkene 2 is postulated.
